Synthesis of reduced graphene oxide nanoscrolls embedded in polypyrrole matrix for supercapacitor applications

被引：27

作者：

Atri, Priyanka ^{[1
]}

Tiwari, Dinesh Chandra ^{[1
]}

Sharma, Rishi ^{[2
]}

机构：

[1] Jiwaji Univ, Sch Studies Phys, Gwalior 474011, MP, India

[2] Cent Elect Engn Res Inst, CSIR, MEMS & Microsensors Grp, Pilani 333031, Rajasthan, India

来源：

SYNTHETIC METALS | 2017年 / 227卷

关键词：

Graphene nanoscrolls; Supercapacitor; Polypyrrole; CARBON NANOSCROLLS; RAMAN-SPECTROSCOPY; POLYMER NANOCOMPOSITES; EFFICIENT SYNTHESIS; HIGHLY EFFICIENT; ENERGY-STORAGE; CHEMICAL ROUTE; COMPOSITES; SHEETS; FABRICATION;

D O I：

10.1016/j.synthmet.2017.03.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Reduced graphene oxide (rGO) nanoscrolls are synthesized in the presence of pyrrole (Py) by using oxidative polymerization method in the presence of sulphuric acid and ammonium persulfate. We report a simple method for the synthesis of rGO nanoscrolls in the presence of pyrrole, and this composite material is used for the supercapacitor applications. Supercapacitor electrodes show good cyclic stability by retaining 88% of the specific capacitance even after 200 cycles. Polypyrrole - reduced graphene oxide (PPy-rGO nanoscrolls) is characterized by Raman, TEM, FESEM, EDX, FTIR, TGA and UV-vis spectroscopy techniques. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：21 / 28

页数：8

共 71 条

[1] Efficient synthesis of graphene sheets using pyrrole as a reducing agent [J].

Amarnath, Chellachamy Anbalagan ;

Hong, Chang Eui ;

Kim, Nam Hoon ;

Ku, Bon-Cheol ;

Kuila, Tapas ;

Lee, Joong Hee .

CARBON, 2011, 49 (11) :3497-3502

[2] Reasons and remedies for the agglomeration of multilayered graphene and carbon nanotubes in polymers [J].

Atif, Rasheed ;

Inam, Fawad .

BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2016, 7 :1174-1196

[3]

Bets KV, 2009, NANO RES, V2, P161, DOI [10.1007/s12274-009-9015-x, 10.1007/S12274-009-9015-X]

[4] Electrochemical performance of a graphene-polypyrrole nanocomposite as a supercapacitor electrode [J].

Bose, Saswata ;

Kim, Nam Hoon ;

Kuila, Tapas ;

Lau, Kin-tak ;

Lee, Joong Hee .

NANOTECHNOLOGY, 2011, 22 (29)

[5] Structure and dynamics of carbon nanoscrolls [J].

Braga, SF ;

Coluci, VR ;

Legoas, SB ;

Giro, R ;

Galvao, DS ;

Baughman, RH .

NANO LETTERS, 2004, 4 (05) :881-884

[6]

Brar VW, 2002, PHYS REV B, V66, DOI 10.1103/PhysRevB.66.155418

[7] A simple mechanical technique to obtain carbon nanoscrolls from graphite nanoplatelets [J].

Carotenuto, Gianfranco ;

Longo, Angela ;

De Nicola, Sergio ;

Camerlingo, Carlo ;

Nicolais, Luigi .

NANOSCALE RESEARCH LETTERS, 2013, 8 :1-6

[8] Raman fingerprint of charged impurities in graphene [J].

Casiraghi, C. ;

Pisana, S. ;

Novoselov, K. S. ;

Geim, A. K. ;

Ferrari, A. C. .

APPLIED PHYSICS LETTERS, 2007, 91 (23)

[9] Second-Order Overtone and Combination Raman Modes of Graphene Layers in the Range of 1690-2150 cm-1 [J].

Cong, Chunxiao ;

Yu, Ting ;

Saito, Riichiro ;

Dresselhaus, Gene F. ;

Dresselhaus, Mildred S. .

ACS NANO, 2011, 5 (03) :1600-1605

[10] Controlled growth of polypyrrole nanotubule/wire in the presence of a cationic surfactant [J].

Dai, Tingyang ;

Yang, Xiaoming ;

Lu, Yun .

NANOTECHNOLOGY, 2006, 17 (12) :3028-3034

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