High performance layered SmBa0.5Sr0.5Co2O5+δ cathode for intermediate-temperature solid oxide fuel cells

被引：12

作者：

Ding, Hanping ^{[1
,2
]}

Xue, Xingjian ^{[2
]}

Liu, Xingqin ^{[1
]}

Meng, Guangyao ^{[1
]}

机构：

[1] USTC, Dept Mat Sci & Engn, Hefei 230026, Peoples R China

[2] Univ S Carolina, Dept Mech Engn, Columbia, SC 29208 USA

来源：

JOURNAL OF POWER SOURCES | 2009年 / 194卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Solid oxide fuel cells; Cathode; Layered perovskite; Interfacial polarization resistance; PEROVSKITE OXIDE; SOFC CATHODES; ELECTROLYTE;

D O I：

10.1016/j.jpowsour.2009.06.055

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The layered SmBa0.5Sr0.5Co2O5+delta (SBSC) perovskite oxide is synthesized by the Pechini method and investigated as a novel cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs). A laboratory-sized Sm0.2Ce0.8O1.9 (SDC)-based tri-layer cell of NiO-SDC/SDC/SBSC is operated from 500 to 700 degrees C fed with humidified H-2 (similar to 3% H2O) as a fuel and the static ambient air as oxidant. A maximum power density of 1147 mW cm(-2) is achieved at 700 degrees C. The interfacial polarization resistance is as low as 1.01, 0.38, 0.16, 0.06 and 0.03 Omega cm(2) at 500, 550, 600, 650 and 700 degrees C, respectively. The experimental results indicate that SBSC is a very promising cathode material for IT-SOFCs. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：815 / 817

页数：3

共 21 条

[11] Prontonic ceramic membrane fuel cells with layered GdBaCO2O5+x cathode prepared by gel-casting and suspension spray [J].

Lin, Bin ;

Zhang, Shangquan ;

Zhang, Linchao ;

Bi, Lei ;

Ding, Hanping ;

Liu, Xingqin ;

Gao, Hanfeng ;

Meng, Guangyao .

JOURNAL OF POWER SOURCES, 2008, 177 (02) :330-333

[12] In situ screen-printed BaZr0.1Ce0.7Y0.2O3-δ electrolyte-based protonic ceramic membrane fuel cells with layered SmBaCo2O5+χ cathode [J].

Lin, Bin ;

Dong, Yingchao ;

Yan, Ruiqiang ;

Zhang, Shangquan ;

Hu, Mingjun ;

Zhou, Yang ;

Meng, Guangyao .

JOURNAL OF POWER SOURCES, 2009, 186 (02) :446-449

[13] Preparation and characterization of graded cathode La0.6Sr0.4Co0.2Fe0.8O3-δ [J].

Liu, Ze ;

Han, Min-Fang ;

Miao, Wen-Ting .

JOURNAL OF POWER SOURCES, 2007, 173 (02) :837-841

[14] A high-performance ammonia-fueled solid oxide fuel cell [J].

Ma, Qianli ;

Peng, Ranran ;

Lin, Yongjing ;

Gao, Hanfeng ;

Meng, Guangyao .

JOURNAL OF POWER SOURCES, 2006, 161 (01) :95-98

[15] CERAMIC FUEL-CELLS [J].

MINH, NQ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (03) :563-588

[16] Oxygen transfer processes in (La,Sr)MnO3/Y2O3-stabilized ZrO2 cathodes:: an impedance spectroscopy study [J].

Murray, EP ;

Tsai, T ;

Barnett, SA .

SOLID STATE IONICS, 1998, 110 (3-4) :235-243

[17] Optimization of the interface polarization of the La2NiO4-based cathode working with the Ce1-xSmxO2-δ electrolyte system [J].

Perez-Coll, D. ;

Aguadero, A. ;

Escudero, M. J. ;

Nunez, P. ;

Daza, L. .

JOURNAL OF POWER SOURCES, 2008, 178 (01) :151-162

[18] Synthesis, electrical and electrochemical properties of Ba0.5Sr0.5Zn0.2Fe0.8O3-δ perovskite oxide for IT-SOFC cathode [J].

Wei, Bo ;

Lue, Zhe ;

Huang, Xiqiang ;

Liu, Mingliang ;

Li, Na ;

Su, Wenhui .

JOURNAL OF POWER SOURCES, 2008, 176 (01) :1-8

[19] Electrochemical characterization and performance evaluation of intermediate temperature solid oxide fuel cell with La0.75Sr0.25CUO2.5-δ cathode [J].

Yu, HC ;

Zhao, F ;

Virkar, AV ;

Fung, KZ .

JOURNAL OF POWER SOURCES, 2005, 152 (01) :22-26

[20] Effect of Gd (Sm) doping on properties of ceria electrolyte for solid oxide fuel cells [J].

Zha, SW ;

Xia, CR ;

Meng, GY .

JOURNAL OF POWER SOURCES, 2003, 115 (01) :44-48

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