The Fe and Zn isotope composition of deep mantle source regions: Insights from Baffin Island picrites

Young (61 Ma) unaltered picrites from Baffin Island, northeast Canada, possess some of the highest He-3/He-4 (up to 50 Ra) seen on Earth, and provide a unique opportunity to study primordial mantle that has escaped subsequent chemical modification. These high-degree partial melts also record anomalously high W-182/W-184 ratios, but their Sr-Nd-Hf-Pb isotopic compositions (including Nd-142) are indistinguishable from those of North Atlantic mid-ocean ridge basalts. New high precision Fe and Zn stable isotope analyses of Baffin Island picrites show limited variability with delta Fe-56 ranging from -0.03 parts per thousand to 0.13 parts per thousand and delta Zn-56 varying from 0.18 parts per thousand to 0.28 parts per thousand. However, a clear inflection is seen in both sets of isotope data around the compo- sition of the parental melt (MgO = 21 wt%; delta Fe-56 = 0.08 +/- 0.04 parts per thousand; and delta Zn-56 = 0.24 +/- 0.03 parts per thousand), with two diverging trends interpreted to reflect the crystallisation of olivine and spinel in low-MgO samples and the accumulation of olivine at higher MgO. Olivine mineral separates are significantly isotopically lighter than their corresponding whole rocks (delta Fe-56 >= -0.62 parts per thousand and delta Zn-56 >= -0.22 parts per thousand), with analyses of individual olivine phenocrysts having extremely variable Fe isotope compositions (delta Fe-56 = -0.01 parts per thousand to -0.80 parts per thousand). By carrying out modelling in three-isotope space, we show that the very negative Fe isotope compositions of olivine phenocryst are the result of kinetic isotope fractionation from disequilibrium diffusional processes. An excellent correlation is observed between delta Fe-56 and delta Zn-56, demonstrating that Zn isotopes are fractionated by the same pro- cesses as Fe in simple systems dominated by magmatic olivine. The incompatible behaviour of Cu during magmatic evolution is consistent with the sulfide-undersaturated nature of these melts. Consequently Zn behaves as a purely lithophile element, and estimates of the bulk Earth Zn isotope composition based on Baffin Island should therefore be robust. The ancient unde- gassed lower mantle sampled at Baffin Island possesses a delta Fe-56 value that is within error of previous estimates of bulk mantle delta Fe-56, however, our estimate of the Baffin mantle delta Zn-56 (0.20 +/- 0.03 parts per thousand) is significantly lower than some previous estimates. Comparison of our new data with those for Archean and Proterozoic komatiites is consistent with the Fe and Zn isotope composition of the mantle remaining constant from at least 3 Ga to the present day. By focusing on large-degree partial melts (e.g. komatiites and picrites) we are potenitally biasing our record to samples that will inevitably have interacted with, entrained and meltedthe ambient shallow mantle during ascent. For a major element such as Fe, that will continuosly participate in melting as it rises through the mantle, the final isotopic compositon of the magama will be a weighted average of the complete melting column. Thus it is unsuprising that minimal Fe isotope variations are seen between localities. In contrast, the unique geochemical signatures (e.g. He and W) displayed by the Baffin Island picrites are inferred to solely originate from the lowermost mantle and will be continuously diluted upon magma ascent. (C) 2018 Elsevier Ltd. All rights reserved.