A Flexible and Porous Ferrocene-Based Gallium MOF with MIL-53 Architecture

被引：14

作者：

Benecke, Jannik ^{[1
]}

Fuss, Alexander ^{[1
]}

Engesser, Tobias A. ^{[1
]}

Stock, Norbert ^{[1
]}

Reinsch, Helge ^{[1
]}

机构：

[1] Univ Kiel, Inst Inorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 2021卷 / 08期

关键词：

Metal-organic frameworks; Flexible frameworks; Adsorption; MIL-53; Ferrocene;

D O I：

10.1002/ejic.202001085

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new gallium based metal-organic framework, denoted as Ga-MIL-53-FcDC, with the chemical formula [Ga(OH)(FeC12H8O4)] was synthesized using the ferrocene containing linker molecule 1,1'-ferrocenedicarboxylic acid (H(2)FcDC, FeC12H10O4). The porous nature of the compound could be confirmed by nitrogen sorption and a specific surface area of 270 m(2)/g was determined. The persistence of the ferrocene complex inside the structure was confirmed by Mossbauer-, EPR and UV/VIS-spectroscopy. Ga-MIL-53-FcDC shows structural flexibility depending on which guest molecule is located in the pores of the compound. The mechanism of structural flexibility was analyzed by means of powder X-ray diffraction adsorbing pyrazine or iodine. The flexibility of the crystal structure can be attributed to the torsion of the GaO6 octahedra in the IBU respective to each other and the torsion of the carboxylate groups of FcDC(2-) relative to the aromatic ring.

引用

页码：713 / 719

页数：7

共 73 条

[51] RAMAN-SPECTRA OF BR-3- AND I-3- ADSORBED ON ZEOLITES [J].

RUBIM, JC ;

SALA, O .

JOURNAL OF RAMAN SPECTROSCOPY, 1981, 11 (05) :320-321

[52] RAMAN-SPECTRA OF CHEMISORBED BROMINE AND IODINE ON ZEOLITES [J].

RUBIM, JC ;

SALA, O .

JOURNAL OF RAMAN SPECTROSCOPY, 1980, 9 (03) :155-156

[53] Comparison of ab initio and density functional calculations of electric field gradients:: The 57Fe nuclear quadrupole moment from Mossbauer data [J].

Schwerdtfeger, P ;

Söhnel, T ;

Pernpointner, M ;

Laerdahl, JK ;

Wagner, FE .

JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (13) :5913-5924

[54] REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].

SHANNON, RD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767

[55] Selective catalytic reduction of NO by cerium-based metal-organic frameworks [J].

Smolders, Simon ;

Jacobsen, Jannick ;

Stock, Norbert ;

De Vos, Dirk E. .

CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (02) :337-341

[56] Unravelling the Redox-catalytic Behavior of Ce4+ Metal-Organic Frameworks by X-ray Absorption Spectroscopy [J].

Smolders, Simon ;

Lomachenko, Kirill A. ;

Bueken, Bart ;

Struyf, Arnaud ;

Bugaev, Aram L. ;

Atzori, Cesare ;

Stock, Norbert ;

Lamberti, Carlo ;

Roeffaers, Maarten B. J. ;

De Vos, Dirk E. .

CHEMPHYSCHEM, 2018, 19 (04) :373-378

[57]

SOHN YS, 1971, J AM CHEM SOC, V93, P3603, DOI 10.1021/ja00744a011

[58] Structure validation in chemical crystallography [J].

Spek, Anthony L. .

ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 :148-155

[59] High-throughput synthesis of phosphonate based inorganic-organic hybrid compounds under hydrothermal conditions [J].

Stock, N ;

Bein, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (06) :749-752

[60]

Stock N., 2004, ANGEW CHEM, V116, P767

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