A Flexible and Porous Ferrocene-Based Gallium MOF with MIL-53 Architecture

被引:14
作者
Benecke, Jannik [1 ]
Fuss, Alexander [1 ]
Engesser, Tobias A. [1 ]
Stock, Norbert [1 ]
Reinsch, Helge [1 ]
机构
[1] Univ Kiel, Inst Inorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
关键词
Metal-organic frameworks; Flexible frameworks; Adsorption; MIL-53; Ferrocene;
D O I
10.1002/ejic.202001085
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new gallium based metal-organic framework, denoted as Ga-MIL-53-FcDC, with the chemical formula [Ga(OH)(FeC12H8O4)] was synthesized using the ferrocene containing linker molecule 1,1'-ferrocenedicarboxylic acid (H(2)FcDC, FeC12H10O4). The porous nature of the compound could be confirmed by nitrogen sorption and a specific surface area of 270 m(2)/g was determined. The persistence of the ferrocene complex inside the structure was confirmed by Mossbauer-, EPR and UV/VIS-spectroscopy. Ga-MIL-53-FcDC shows structural flexibility depending on which guest molecule is located in the pores of the compound. The mechanism of structural flexibility was analyzed by means of powder X-ray diffraction adsorbing pyrazine or iodine. The flexibility of the crystal structure can be attributed to the torsion of the GaO6 octahedra in the IBU respective to each other and the torsion of the carboxylate groups of FcDC(2-) relative to the aromatic ring.
引用
收藏
页码:713 / 719
页数:7
相关论文
共 73 条
[1]   In(OH)BDC•0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure [J].
Anokhina, EV ;
Vougo-Zanda, M ;
Wang, XQ ;
Jacobson, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :15000-15001
[2]   Why is Ferrocene so Exceptional? [J].
Astruc, Didier .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (01) :6-29
[3]   Functional porous material - MOFs - Metal organic frame structure [J].
Bauer, Sebastian ;
Stock, Norbert .
CHEMIE IN UNSERER ZEIT, 2008, 42 (01) :12-19
[4]   Polymorphous Indium Metal-Organic Frameworks Based on a Ferrocene Linker: Redox Activity, Porosity, and Structural Diversity [J].
Benecke, Jannik ;
Grape, Erik Svensson ;
Fuss, Alexander ;
Woehlbrandt, Stephan ;
Engesser, Tobias A. ;
Inge, A. Ken ;
Stock, Norbert ;
Reinsch, Helge .
INORGANIC CHEMISTRY, 2020, 59 (14) :9969-9978
[5]   A porous and redox active ferrocenedicarboxylic acid based aluminium MOF with a MIL-53 architecture [J].
Benecke, Jannik ;
Mangelsen, Sebastian ;
Engesser, Tobias A. ;
Weyrich, Thomas ;
Junge, Jannik ;
Stock, Norbert ;
Reinsch, Helge .
DALTON TRANSACTIONS, 2019, 48 (44) :16737-16743
[6]   Infrared spectra of pyrazine, pyrimidine and pyridazine in solid argon [J].
Breda, S ;
Reva, ID ;
Lapinski, L ;
Nowak, MJ ;
Fausto, R .
JOURNAL OF MOLECULAR STRUCTURE, 2006, 786 (2-3) :193-206
[7]   Redox-active metal-organic frameworks for energy conversion and storage [J].
Calbo, Joaquin ;
Golomb, Matthias J. ;
Walsh, Aron .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (28) :16571-16597
[8]   Proton-Coupled Electron Transport in Anthraquinone-Based Zirconium Metal Organic Frameworks [J].
Celis-Salazar, Paula J. ;
Epley, Charity C. ;
Ahrenholtz, Spencer R. ;
Maza, William A. ;
Usov, Pavel M. ;
Morris, Amanda J. .
INORGANIC CHEMISTRY, 2017, 56 (22) :13741-13747
[9]   Bismuth-ferrocene carboxylates: synthesis and structure [J].
Chandrasekhar, Vadapalli ;
Metre, Ramesh K. .
DALTON TRANSACTIONS, 2012, 41 (38) :11684-11691
[10]   Coordination polymers containing ferrocene backbone. Synthesis, structure and electrochemistry [J].
Chandrasekhar, Vadapalli ;
Thirumoorthi, Ramalingam .
DALTON TRANSACTIONS, 2010, 39 (10) :2684-2691