Stepwise formation of organometallic macrocycles, prisms and boxes from Ir, Rh and Ru-based half-sandwich units

被引：307
作者：
Han, Ying-Feng [1 ]
Jia, Wei-Guo [1 ]
Yu, Wei-Bin [1 ]
Jin, Guo-Xin [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 12期
基金：
美国国家科学基金会;
关键词：
MOLECULAR RECTANGLES; METALLO-PRISMS; COORDINATION CHEMISTRY; RHODIUM COMPLEXES; IRIDIUM; SYMMETRY; BEARING; CAGES; NANOSTRUCTURES; ARCHITECTURES;
D O I：
10.1039/b901649j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Over the past decade, supramolecular compounds with organometallic Ir, Rh, Ru based half-sandwich complexes have received considerable attention as materials with a variety of potential applications. The major emphasis of this tutorial review lies on the self-assembly of such organometallic half-sandwich molecular rectangles, prisms and cages with half-sandwich corners and two different rigid bifunctional ligands using an approach of stepwise construction. Synthetic methods and the structural and functional properties of the target complexes are discussed in detail.
引用
收藏
页码：3419 / 3434
页数：16
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