Metal-Free: An Efficient and Selective Catalytic Aerobic Oxidation of Hydrocarbons with Oxime and N-Hydroxyphthalimide

被引：60
|
作者：
Zheng, Gengxiu [1 ]
Liu, Chunhong [1 ]
Wang, Qiufen [1 ]
Wang, Mingyu [1 ]
Yang, Guanyu [2 ]
机构：
[1] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 16期
关键词：
aerobic oxidation; catalyst design; dimethylglyoxime; hydrocarbons; N-hydroxyphthalimide; C-H BONDS; ELECTRON-TRANSFER; HYDROGEN ABSTRACTION; MOLECULAR-OXYGEN; NHPI; ALDEHYDES; SYSTEM;
D O I：
10.1002/adsc.200900509
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A non-metal catalytic system consisting of dimethylglyoxime (DMG) and N-hydroxyphthalimide (NHPI) for the selective oxidation of hydrocarbons with dioxygen is described. The synergistic effect of DMG and NHPI ensures its efficient catalytic ability: 82.1% conversion of ethylbenzene with 94.9% selectivity for acetophenone could be obtained at 80 degrees C under 0.3 MPa of dioxygen in 10 h. Several hydrocarbons were efficiently oxidized to their corresponding oxygenated products under mild conditions.
引用
收藏
页码：2638 / 2642
页数：5
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