Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

被引：110
作者：
Liu, Kai-Jian [1 ]
Wang, Zheng [1 ]
Lu, Ling-Hui [1 ]
Chen, Jin-Yang [2 ]
Zeng, Fei [1 ]
Lin, Ying-Wu [2 ]
Cao, Zhong [3 ]
Yu, Xianyong [4 ]
He, Wei-Min [1 ]
机构：
[1] Hunan Univ Sci & Engn, Dept Chem & Bioengn, Yongzhou 425100, Peoples R China
[2] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Duns, Changsha 410114, Peoples R China
[4] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China
来源：
GREEN CHEMISTRY | 2021年 / 23卷 / 01期
关键词：
INDUCED DEOXYGENATIVE C2-SULFONYLATION; REDUCTIVE MINISCI REACTION; QUINOLINE N-OXIDES; RADICAL CYCLIZATION; ELECTRON-TRANSFER; OXIDATION; SULFONES; QUINOXALIN-2(1H)-ONES; SULFOXIDES; AMBIENT;
D O I：
10.1039/d0gc02663h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction.
引用
收藏
页码：496 / 500
页数：5
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