Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri-annulations: efficient synthesis of 1,3,6,8-tetraazapyrenes

被引：20

作者：

Aksenov, Alexander V. ^{[1
]}

Ovcharov, Dmitrii S. ^{[1
]}

Aksenov, Nicolai A. ^{[1
,2
]}

Aksenov, Dmitrii A. ^{[1
]}

Nadein, Oleg N. ^{[1
]}

Rubin, Michael ^{[1
,3
]}

机构：

[1] North Caucasus Fed Univ, Dept Chem, 1a Pushkin St, Stavropol 355009, Russia

[2] Peoples Friendship Univ Russia RUDN Univ, Dept Organ Chem, 6 Miklukho Maklaya St, Moscow 117198, Russia

[3] Univ Kansas, Dept Chem, 1251 Wescoe Hall Dr, Lawrence, KS 66045 USA

来源：

RSC ADVANCES | 2017年 / 7卷 / 48期

基金：

俄罗斯基础研究基金会;

关键词：

THIN-FILM TRANSISTORS; ONE-POT SYNTHESIS; CHANNEL ORGANIC SEMICONDUCTORS; 3-SUBSTITUTED; 2-QUINOLONES; PERYLENE BISIMIDES; PERIMIDINES; ACENES; PHOTOVOLTAICS; ACETAMINATION; BENZOXAZOLES;

D O I：

10.1039/c7ra04751g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment.

引用

页码：29927 / 29932

页数：6

共 42 条

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