Double metal cyanides as heterogeneous Lewis acid catalysts for nitrile synthesis via acid-nitrile exchange reactions

被引：11
|
作者：
Marquez, Carlos [1 ]
Corbet, Matthieu [2 ]
Smolders, Simon [1 ]
Marion, Philippe [2 ]
De Vos, Dirk [1 ]
机构：
[1] Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Su, Celestijnenlaan 200F, B-3001 Leuven, Belgium
[2] Solvay Rech & Innovat Ctr Lyon, 85 Rue Freres Perret,BP62, F-69192 St Fons, France
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 86期
关键词：
PRUSSIAN BLUE ANALOGS; CARBOXYLIC-ACIDS; FATTY-ACIDS; CRYSTAL; POLYMERIZATION; ESTERIFICATION; CHEMISTRY; ALCOHOLS; OXIDE; ZINC;
D O I：
10.1039/c9cc05382d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of transition metal-based double metal cyanides (DMCs) were studied as catalysts for the synthesis of nitriles via acid-nitrile exchange reaction. The best nitrile yields were obtained with Co-3[Co(CN6)](2) DMC, which proved to be a versatile, stable, reusable and highly active catalyst, exhibiting an activity comparable to that of homogeneous Lewis acid catalysts.
引用
收藏
页码：12984 / 12987
页数：4
相关论文
共 50 条
  • [31] Monomeric metal aqua complexes in the interlayer space of montmorillonites as strong Lewis acid catalysts for heterogeneous carbon-carbon bond-forming reactions
    Kawabata, T
    Kato, M
    Mizugaki, T
    Ebitani, K
    Kaneda, K
    CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (01) : 288 - 297
  • [32] High-yield continuous production of nicotinic acid via nitrile hydratase-amidase cascade reactions using cascade CSMRs
    Cantarella, L.
    Gallifuoco, A.
    Malandra, A.
    Martinkova, L.
    Spera, A.
    Cantarella, M.
    ENZYME AND MICROBIAL TECHNOLOGY, 2011, 48 (4-5) : 345 - 350
  • [33] A DFT study of the role of Lewis acid catalysts in the mechanism of the 1,3-dipolar cycloaddition of nitrile imines towards electron-deficient acryloyl derivatives
    Domingo, Luis R.
    Jose Aurell, M.
    Jalal, Rachid
    Esseffar, M'hamed
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2012, 986 : 6 - 13
  • [34] Synthesis of novel silicon-containing compounds via Lewis acid-catalyzed reactions
    Jung, IN
    Yoo, BR
    ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 53, 2005, 53 : 41 - 59
  • [35] Metal Halide Hydrates as Lewis Acid Catalysts for the Conjugated Friedel-Crafts Reactions of Indoles and Activated Olefins
    Schwalm, Cristiane S.
    Ceschi, Marco Antonio
    Russowsky, Dennis
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2011, 22 (04) : 623 - U381
  • [36] Catalytic C-O bond hydrogenolysis by tandem homogeneous metal Lewis acid plus heterogeneous hydrogenation catalysts
    Li, Zhi
    Assary, Rajeev S.
    Atesin, Abdurrahman C.
    Curtiss, Larry A.
    Marks, Tobin J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [37] Group 13 Lewis acid catalyzed synthesis of metal oxide nanocrystals via hydroxide transmetallation
    Gibson, Noah J.
    Bredar, Alexandria R. C.
    Chakraborty, Nilave
    Farnum, Byron H.
    NANOSCALE, 2021, 13 (26) : 11505 - 11517
  • [38] Hydroxyapatite-bound cationic ruthenium complexes as novel heterogeneous Lewis acid catalysts for Diels-Alder and aldol reactions
    Mori, K
    Hara, T
    Mizugaki, T
    Ebitani, K
    Kaneda, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) : 11460 - 11461
  • [39] Hydroxyapatite-bound cationic ruthenium complexes as novel heterogeneous Lewis acid catalysts for Diels-Alder and aldol reactions
    1600, American Chemical Society (125):
  • [40] Application of chiral ligands: carbohydrates, nucleoside-lanthanides and other Lewis acid complexes to control regio- and stereoselectivity of the dipolar cycloaddition reactions of nitrile oxides and esters
    Gucma, Miroslaw
    Golebiewski, W. Marek
    Krawczyk, Maria
    RSC ADVANCES, 2015, 5 (17) : 13112 - 13124
12345