Double metal cyanides as heterogeneous Lewis acid catalysts for nitrile synthesis via acid-nitrile exchange reactions

被引：11

作者：

Marquez, Carlos ^{[1
]}

Corbet, Matthieu ^{[2
]}

Smolders, Simon ^{[1
]}

Marion, Philippe ^{[2
]}

De Vos, Dirk ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Su, Celestijnenlaan 200F, B-3001 Leuven, Belgium

[2] Solvay Rech & Innovat Ctr Lyon, 85 Rue Freres Perret,BP62, F-69192 St Fons, France

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 86期

关键词：

PRUSSIAN BLUE ANALOGS; CARBOXYLIC-ACIDS; FATTY-ACIDS; CRYSTAL; POLYMERIZATION; ESTERIFICATION; CHEMISTRY; ALCOHOLS; OXIDE; ZINC;

D O I：

10.1039/c9cc05382d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of transition metal-based double metal cyanides (DMCs) were studied as catalysts for the synthesis of nitriles via acid-nitrile exchange reaction. The best nitrile yields were obtained with Co-3[Co(CN6)](2) DMC, which proved to be a versatile, stable, reusable and highly active catalyst, exhibiting an activity comparable to that of homogeneous Lewis acid catalysts.

引用

页码：12984 / 12987

页数：4

共 50 条

[21] Assessment on the double role of the transition metal salts on the acetalization of furfural: Lewis and Bronsted acid catalysts
da Silva, Marcio Jose
Teixeira, Milena Galdino
MOLECULAR CATALYSIS, 2018, 461 : 40 - 47
[22] Synthesis of pyroglutamic acid derivatives via double michael reactions of alkynones
Scansetti, Myriam
Hu, Xiangping
McDermott, Benjamin P.
Lam, Hon Wai
ORGANIC LETTERS, 2007, 9 (11) : 2159 - 2162
[23] Diastereoselective synthesis of highly substituted 2,5-diaminohexanes via nitrile oxide cycloaddition to a vinylogous amino acid
Schreiner, EP
Gstach, H
SYNLETT, 1996, (11) : 1131 - &
[24] SYNTHESIS OF THIAZOLE DERIVATIVES VIA LEWIS-ACID PROMOTED REACTIONS OF DIAZOPYRUVATE WITH THIOAMIDES
KIM, HS
KWON, IC
LEE, JY
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1995, 16 (01) : 4 - 5
[25] Diastereoselective Synthesis of Highly Substituted 2,5-Diaminohexanes via Nitrile Oxide Cycloaddition to a Vinylogous Amino Acid
Schreiner, E. P.
Gstach, H.
Synlett, (11):
[26] Primary amine-metal Lewis acid bifunctional catalysts: the application to asymmetric direct aldol reactions
Xu, Zhenghu
Daka, Philias
Wang, Hong
CHEMICAL COMMUNICATIONS, 2009, (44) : 6825 - 6827
[27] Metal bis(perfluorooctanesulfonyl)amides as highly efficient Lewis acid catalysts for fluorous biphase organic reactions
Hao, XH
Yoshida, A
Nishikido, J
JOURNAL OF FLUORINE CHEMISTRY, 2006, 127 (02) : 193 - 199
[28] Metal-organic frameworks as heterogeneous solid acid catalysts for fixed-bed reactions
Ma, Shengqian
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[29] Total Synthesis of Guajava']javadimer A via Lewis Acid-Catalyzed Cascade Double Hetero-Diels-Alder Reactions
Duan, Shengfu
Zhang, Xing
Li, Xiangxin
Chi, Zhiyong
Xie, Zhixiang
ORGANIC LETTERS, 2023, 25 (38) : 6987 - 6992
[30] Regio- and diastereo-selective formation of isoxazoline derivatives by Lewis acid mediated 1,3-dipolar cycloaddition reactions of nitrile oxide
Hayashi, Saori
Mori, Akira
Nishina, Masatoshi
Sumimoto, Masanori
Hori, Kenzi
Yamamoto, Hidetoshi
JOURNAL OF CHEMICAL RESEARCH, 2007, (07) : 394 - 396

← 1 2 3 4 5 →