Synthesis and Structure of a Trinuclear Platinum Complex with μ3-Silylyne Ligands Derived from a Disilane

被引：22
|
作者：
Arii, Hidekazu [1 ]
Takahashi, Makiko [1 ]
Nanjo, Masato [1 ]
Mochida, Kunio [1 ]
机构：
[1] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 16期
关键词：
TRANSITION-METAL-COMPLEXES; SILYLENE; SILICON; GENERATION; REACTIVITY; HYDROSILANES; DIMERIZATION; MONOMERS; DIMERS;
D O I：
10.1021/om900533z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The platinum complex [Pt(dppe)(eta(2)-C2H4) (1) reacted with the disilane H2SiMeSiMe3, affording the bis-(mu-silylene)triplatinum complex [Pt-3(dppe)(3)(mu(3)-SiMe)(2)] (4) by a stepwise Si-H and Si-Si bond activation.
引用
收藏
页码：4629 / 4631
页数：3
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