Comparative study on the inclusion interaction between meso-tetrakis(4-N-ethylpyridiniurmyl) porphyrin and β-cyclodextrin derivatives

被引：0
|
作者：
Guo, XL [1 ]
Shuang, SM [1 ]
Chao, JB [1 ]
Li, DX [1 ]
机构：
[1] Shanxi Univ, Sch Chem & Chem Engn, Inst Adv Chem, Taiyuan 030006, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2004年 / 15卷 / 08期
关键词：
meso-tetrakis (4-N-ethylpyridiniurmyl) porphyrin (TEPyP); cyclodextrin; absorption; fluorescence; nuclear magnetic resonance (NMR);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The interaction of beta-cyclodextrin (beta-CD) and the modified cyclodextrins, hydroxy propyl-beta-cyclodextrin (HP-beta-CD), sulfobutylether-beta-cyclodextrin (SBE-beta-CD) and synthesized meso-tetrakis(4-N-ethylpyridiniurmyl)porphyrin (TEPyP) in aqueous solution has been studied by spectroscopic methods systematically. A significant change in fluorescence and absorption properties has been observed in the presence of beta-CD, HP-beta-CD and SBE-beta-CD. The stoichiometry and formation constants have been determined by the steady-state fluorescence technique. The results showed that the beta-CD derivatives were prior to the native beta-CD and the hydrogen bonding and static electric forces played important roles in the formation of the inclusion complexes. The conformation was further confirmed by NMR spectroscopy.
引用
收藏
页码：961 / 964
页数：4
相关论文
共 24 条
  • [21] Aggregation of meso-tetrakis(4-N-methyl-pyridiniumyl) porphyrin in its free base, Fe(III) and Mn(III) forms due to the interaction with DNA in aqueous solutions: Optical absorption, fluorescence and light scattering studies
    Gandini, SCM
    Borissevitch, IE
    Perussi, JR
    Imasato, H
    Tabak, M
    JOURNAL OF LUMINESCENCE, 1998, 78 (01) : 53 - 61
  • [22] Thermodynamic study of the interaction between 5,10,15,20-tetrakis-(N-methyl-4-pyridyl)porphyrin tetraiodine and sodium dodecyl sulfate
    Almeida, C. M. R.
    Nascimento, B. F. O.
    Pineiro, M.
    Valente, A. J. M.
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2015, 480 : 279 - 286
  • [23] Investigation of the interactions between Pt(II) and Pd(II) derivatives of 5,10,15,20-tetrakis (N-methyl-4-pyridyl) porphyrin and G-quadruplex DNA
    Navin C. Sabharwal
    Oscar Mendoza
    John M. Nicoludis
    Thomas Ruan
    Jean-Louis Mergny
    Liliya A. Yatsunyk
    JBIC Journal of Biological Inorganic Chemistry, 2016, 21 : 227 - 239
  • [24] Investigation of the interactions between Pt(II) and Pd(II) derivatives of 5,10,15,20-tetrakis (N-methyl-4-pyridyl) porphyrin and G-quadruplex DNA
    Sabharwal, Navin C.
    Mendoza, Oscar
    Nicoludis, John M.
    Ruan, Thomas
    Mergny, Jean-Louis
    Yatsunyk, Liliya A.
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2016, 21 (02): : 227 - 239
123