KINETICS AND MECHANISM OF ELECTRON TRANSFER REACTIONS. OXIDATION OF PYRIDINE BY PEROXOMONOPHOSPHATE IN AQUEOUS ACID MEDIUM

被引：0

作者：

Agrawal, A. ^{[1
]}

Deepmala ^{[1
]}

Sharma, P. ^{[1
]}

Khandelwal, C. L. ^{[1
]}

Sharma, P. D. ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

OXIDATION COMMUNICATIONS | 2013年 / 36卷 / 04期

关键词：

kinetics; mechanism; oxidation pyridine; peroxomonophosphate; PERCHLORIC-ACID; PERMANGANATE OXIDATION; PEROXODIPHOSPHATE IONS; HYDROLYSIS; PEROXIDE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of pyridine by peroxomonophosphate has been studied in acid perchlorate medium. The oxidation product of the substrate has been confirmed to be pyridine N-oxide spectrally. The reaction is second order, viz, first order with respect to each reactant. A suitable reaction mechanism has been suggested in agreement to the experimental observations.

引用

页码：881 / 889

页数：9

共 18 条

[1] DISSOCIATION CONSTANTS AND KINETICS OF HYDROLYSIS OF PEROXYMONOPHOSPHORIC ACID [J].

BATTAGLIA, CJ ;

EDWARDS, JO .

INORGANIC CHEMISTRY, 1965, 4 (04) :552-+

[2] KINETICS AND MECHANISM OF OXIDATIONS BY PEROXYDIPHOSPHATE .2. OXIDATION OF BROMIDE IN AQUEOUS PERCHLORIC-ACID SOLUTION [J].

BHARADWAJ, LM ;

SHARMA, DN ;

GUPTA, YK .

INORGANIC CHEMISTRY, 1976, 15 (07) :1695-1697

[3]

BOYLAND E., 1957, J CHEM SOC, P4869

[4] PERMANGANATE OXIDATION OF URACIL AND CYTOSINE AND THEIR 1-SUBSTITUTED DERIVATIVES [J].

CHATAMRA, B ;

JONES, AS .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (FEB) :811-&

[5] HYDROLYSIS OF PEROXOPHOSPHATES [J].

GOH, SH ;

HESLOP, RB ;

LETHBRID.JW .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (10) :1302-&

[6] NUCLEOTIDE SEQUENCE IN DEOXYRIBONUCLEIC ACIDS 6. PREPARATION + REACTIONS OF PERMANGANATE-OXIDISED DEOXYRIBONUCLEIC ACID [J].

JONES, AS ;

WALKER, RT ;

ROSS, GW ;

TAKEMURA, S ;

THOMPSON, TW .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JAN) :373-&

[7] PERMANGANATE OXIDATION OF NUCLEOSIDES [J].

JONES, AS ;

WALKER, RT .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (JUL) :3554-&

[8] KINETICS AND MECHANISM OF OXIDATIONS BY PEROXODIPHOSPHATE IONS .3. OXIDATION OF HYPOPHOSPHITE IN AQUEOUS PERCHLORIC-ACID BY HYDROLYTIC PRODUCT PEROXOMONOPHOSPHATE IN A CONSECUTIVE REACTION [J].

KAPOOR, S ;

GUPTA, YK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09) :862-865

[9] KINETICS AND MECHANISM OF OXIDATIONS BY PEROXODIPHOSPHATE IONS .1. OXIDATION OF ARSENIC(III) IN AQUEOUS PERCHLORIC-ACID [J].

KAPOOR, S ;

GUPTA, YK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (05) :473-476

[10] KINETICS AND MECHANISM OF OXIDATIONS BY PEROXODIPHOSPHATE .4. STOICHIOMETRY AND KINETICS OF OXIDATIONS OF ANTIMONY(III), HYDRAZINE AND NITRITE IN AQUEOUS PERCHLORIC-ACID MEDIUM [J].

KAPOOR, S ;

GUPTA, YK .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (06) :1019-1021

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