Copper-Catalyzed α-Aminoxylation of Ketones with 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO)

被引：27

作者：

Xie, Ye-Xiang ^{[1
]}

Song, Ren-Jie ^{[1
]}

Liu, Yu ^{[1
]}

Liu, Yan-Yun ^{[1
]}

Xiang, Jian-Nan ^{[1
]}

Li, Jin-Heng ^{[1
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 17期

基金：

中国博士后科学基金;

关键词：

alpha-aminoxylation; C-H cleavage; copper; ketones; TEMPO; 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO); RADICAL CHEMISTRY; ORGANOCATALYSIS; ALDEHYDES; ROUTE;

D O I：

10.1002/adsc.201300630

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient copper-catalyzed -aminoxylation of ketones with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) is presented for the synthesis of 2-aryloxy-1-aryl-2-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethanones in moderate to excellent yields. It is noteworthy that the copper/iron (Cu/Fe) catalyst can be recovered and reused several times with high catalytic reactivity.

引用

页码：3387 / 3390

页数：4

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