Determination of BPA, BPB, BPF, BADGE and BFDGE in canned energy drinks by molecularly imprinted polymer cleaning up and UPLC with fluorescence detection

被引：107

作者：

Gallo, Pasquale ^{[1
]}

Di Marco Pisciottano, Ilaria ^{[1
]}

Esposito, Francesco ^{[2
]}

Fasano, Evelina ^{[2
]}

Scognamiglio, Gelsomina ^{[2
]}

Mita, Gustavo Damiano ^{[3
]}

Cirillo, Teresa ^{[2
]}

机构：

[1] Ist Zooprofilatt Sperimentale Mezzogiorno, Dipartimento Chim, Via Salute 2, I-80055 Portici, NA, Italy

[2] Univ Naples Federico II, Dept Agr Sci, Via Univ 100, I-80055 Portici, NA, Italy

[3] Consorzio Interuniv Ist Nazl Biostrutture & Biosi, Via P Castellino 111, I-80131 Naples, Italy

来源：

FOOD CHEMISTRY | 2017年 / 220卷

关键词：

Bisphenols; Energy drink; UPLC; Molecularly imprinted polymers; BISPHENOL-A; HUMAN EXPOSURE; UNITED-STATES; ANALOGS; QUANTIFICATION; PERFORMANCE; CONSUMPTION; MIGRATION; BEVERAGES; ALCOHOL;

D O I：

10.1016/j.foodchem.2016.10.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new method for simultaneous determination of five bisphenols in canned energy drinks by UPLC with fluorescence detection, after clean up on molecularly imprinted polymers, is herein described. The method was validated at two concentration levels, calculating trueness, repeatability and within-laboratory reproducibility, specificity, linearity of detector response, the limits of quantifications and the limits of detection for each bisphenol. The method is specific, reliable and very sensitive, allowing for determination of bisphenol F diglycidyl ether (BFDGE), bisphenol A (BPA), bisphenol B (BPB), bisphenol F (BPF) and bisphenol A diglycidyl ether (BADGE) down to 0.50 ng/mL; it was employed to determine contamination levels from these bisphenols in forty energy drinks of different brands, collected from the market in Naples. BPA was detected in 17 out of 40 samples (42.5%); in some energy drinks also BPF, BADGE and BFDGE were determined. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：406 / 412

页数：7

共 36 条

[1] The effects of Red Bull Energy Drink on human performance and mood [J].