The chlorination of the [Al13]- cluster and the stepwise formation of its intermediate products, [Al11]- [Al9]-, and [Al7]-:: A model reaction for the oxidation of metals?

被引：30

作者：

Burgert, R

Schnöckel, H

Olzmann, M

Bowen, KH

机构：

[1] Univ Karlsruhe, Inst Inorgan Chem, D-76128 Karlsruhe, Germany

[2] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany

[3] Johns Hopkins Univ, Dept Chem & Mat Sci, Baltimore, MD 21218 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 09期

关键词：

aluminium; chlorine; cluster compounds; density functional calculations; mass spectrometry;

D O I：

10.1002/anie.200502957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Watch your step! The individual steps during the chlorination of [Al 13]- clusters via [Al11]-, [Al 9]-, and [Al7]- intermediates (see picture) can be "visualized" by means of Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. The reaction can be interpreted as a model reaction for the chlorination of bulk aluminum. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1476 / 1479

页数：4