N-Heteropolycyclic Compounds from the Formal Intramolecular (4+1)-Cycloaddition of Chromium Aminocarbenes

被引：15

作者：

Dery, Martin ^{[1
]}

Lefebvre, Louis-Philippe D. ^{[1
]}

Aissa, Kevin ^{[1
]}

Spino, Claude ^{[1
]}

机构：

[1] Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 21期

基金：

加拿大自然科学与工程研究理事会;

关键词：

FISCHER CARBENE COMPLEXES; CYCLOADDITION REACTIONS; VINYLCYCLOPROPANE DERIVATIVES; CYCLOPENTENE DERIVATIVES; 5-MEMBERED CARBOCYCLES; ALKYNES; STEREOSELECTIVITY; REARRANGEMENT; HETEROCYCLES;

D O I：

10.1021/ol4025887

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chromium aminocarbenes tethered to dienes of all three electronic natures undergo an efficient intramolecular (4 + 1)-cycloaddition to give N-heteropolycyclic compounds. Ligands on chromium had a profound effect on the course of the reaction.

引用

页码：5456 / 5459

页数：4

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