Growth and Structure of Sr3Yb2(BO3)4 Crystal

被引：0

作者：

Lin Fu-Lin ^{[1
,2
]}

Huang Jian-Hua ^{[1
]}

Gong Xing-Hong ^{[1
]}

Huang Xiao-Ying ^{[1
]}

Lin Yan-Fu ^{[1
]}

Chen Yu-Jin ^{[1
]}

Huang Yi-Dong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 32卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Sr3YP2(BO3)(4); Czochralski method; crystal structure; LASER OPERATION;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Sr3Yb2(BO3)(4)ingle crystal was obtained by the Czochralski method. The structure of Sr3Yb2(BO3)(4)ystal was determined by single-crystal X-ray diffraction. The compound crystallizes in orthorhombic, space group Pnma with a = 7.3750(8), b = 15.9265(14), c = 8.6776(9) angstrom, V= 1019.25(18) angstrom(3), M-r= 844.18, Z= 4, D-c 5.501 g/cm(3), lambda(MoK alpha) = 0.71073 angstrom,mu = 33.835 mm(-1) F(000) = 1480, the final R= 0.0339 and wR= 0.0907 for 1090 observed reflections with I> 2 sigma(I). The structure features a three-dimensional framework composed of isolated BO3 planar triangles bridged by YbO(8)and SrO8 polyhedra. The Sr2+ and Yb3+ occupy statistically three independent sites with a C, and two Ci local symmetries.

引用

页码：434 / 438

页数：5

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