Aromatic porous-honeycomb electrodes for a sodium-organic energy storage device

被引：330
作者：
Sakaushi, Ken [1 ,2 ,3 ]
Hosono, Eiji [3 ]
Nickerl, Georg [2 ]
Gemming, Thomas [1 ]
Zhou, Haoshen [3 ]
Kaskel, Stefan [2 ]
Eckert, Juergen [1 ,4 ]
机构：
[1] IFW Dresden, Inst Complex Mat, D-01069 Dresden, Germany
[2] Tech Univ Dresden, Dept Inorgan Chem, D-01069 Dresden, Germany
[3] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
[4] Tech Univ Dresden, Inst Mat Sci, D-01069 Dresden, Germany
来源：
NATURE COMMUNICATIONS | 2013年 / 4卷
关键词：
GRAPHITIC CARBON NITRIDE; ION; LITHIUM; INTERCALATION; RAMAN; HARD; CHALLENGES; BATTERIES; INSERTION; POLYMERS;
D O I：
10.1038/ncomms2481
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Rechargeable batteries using organic electrodes and sodium as a charge carrier can be high-performance, affordable energy storage devices due to the abundance of both sodium and organic materials. However, only few organic materials have been found to be active in sodium battery systems. Here we report a high-performance sodium-based energy storage device using a bipolar porous organic electrode constituted of aromatic rings in a porous-honeycomb structure. Unlike typical organic electrodes in sodium battery systems, the bipolar porous organic electrode has a high specific power of 10kWkg(-1), specific energy of 500Whkg(-1), and over 7,000 cycle life retaining 80% of its initial capacity in half-cells. The use of bipolar porous organic electrode in a sodium-organic energy storage device would significantly enhance cost-effectiveness, and reduce the dependency on limited natural resources. The present findings suggest that bipolar porous organic electrode provides a new material platform for the development of a rechargeable energy storage technology.
引用
收藏
页数：7
相关论文
共 61 条
  • [1] Porous graphenes: two-dimensional polymer synthesis with atomic precision
    Bieri, Marco
    Treier, Matthias
    Cai, Jinming
    Ait-Mansour, Kamel
    Ruffieux, Pascal
    Groening, Oliver
    Groening, Pierangelo
    Kastler, Marcel
    Rieger, Ralph
    Feng, Xinliang
    Muellen, Klaus
    Fasel, Roman
    [J]. CHEMICAL COMMUNICATIONS, 2009, (45) : 6919 - 6921
  • [2] From biomass to a renewable LixC6O6 organic electrode for sustainable Li-ion batteries
    Chen, Haiyan
    Armand, Michel
    Demailly, Gilles
    Dolhem, Franck
    Poizot, Philippe
    Tarascon, Jean-Marie
    [J]. CHEMSUSCHEM, 2008, 1 (04) : 348 - 355
  • [3] High-Performance Sodium-Ion Pseudocapacitors Based on Hierarchically Porous Nanowire Composites
    Chen, Zheng
    Augustyn, Veronica
    Jia, Xilai
    Xiao, Qiangfeng
    Dunn, Bruce
    Lu, Yunfeng
    [J]. ACS NANO, 2012, 6 (05) : 4319 - 4327
  • [4] Challenges for Na-ion Negative Electrodes
    Chevrier, V. L.
    Ceder, G.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (09) : A1011 - A1014
  • [5] Conjugated Microporous Polymers
    Cooper, Andrew I.
    [J]. ADVANCED MATERIALS, 2009, 21 (12) : 1291 - 1295
  • [6] Redox flow cells for energy conversion
    de Leon, C. Ponce
    Frias-Ferrer, A.
    Gonzalez-Garcia, J.
    Szanto, D. A.
    Walsh, F. C.
    [J]. JOURNAL OF POWER SOURCES, 2006, 160 (01) : 716 - 732
  • [7] ELECTROCHEMICAL INTERCALATION OF SODIUM IN NAXCOO2 BRONZES
    DELMAS, C
    BRACONNIER, JJ
    FOUASSIER, C
    HAGENMULLER, P
    [J]. SOLID STATE IONICS, 1981, 3-4 (AUG) : 165 - 169
  • [8] A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
    Ellis, B. L.
    Makahnouk, W. R. M.
    Makimura, Y.
    Toghill, K.
    Nazar, L. F.
    [J]. NATURE MATERIALS, 2007, 6 (10) : 749 - 753
  • [9] Sodium and sodium-ion energy storage batteries
    Ellis, Brian L.
    Nazar, Linda F.
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2012, 16 (04) : 168 - 177
  • [10] Raman spectrum of graphene and graphene layers
    Ferrari, A. C.
    Meyer, J. C.
    Scardaci, V.
    Casiraghi, C.
    Lazzeri, M.
    Mauri, F.
    Piscanec, S.
    Jiang, D.
    Novoselov, K. S.
    Roth, S.
    Geim, A. K.
    [J]. PHYSICAL REVIEW LETTERS, 2006, 97 (18)
1234567