The Rational Design of a Single-Component Photocatalyst for Gas-Phase CO2 Reduction Using Both UV and Visible Light

被引：212
作者：
Hoch, Laura B. [1 ]
Wood, Thomas E. [2 ]
O'Brien, Paul G. [1 ]
Liao, Kristine [1 ]
Reyes, Laura M. [1 ]
Mims, Charles A. [2 ]
Ozin, Geoffrey A. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Mat Chem Res Grp, 80 St George St, Toronto, ON M5S 3H6, Canada
[2] Univ Toronto, Dept Chem Engn & Appl Chem, Toronto, ON M5S 3E5, Canada
来源：
ADVANCED SCIENCE | 2014年 / 1卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
ARTIFICIAL PHOTOSYNTHESIS; OXYGEN VACANCY; CARBON-DIOXIDE; TIO2; SEMICONDUCTORS; PHOTOREDUCTION; HYDROGENATION; CATALYSTS; VALENCE;
D O I：
10.1002/advs.201400013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The solar-to-chemical energy conversion of greenhouse gas CO2 into carbon-based fuels is a very important research challenge, with implications for both climate change and energy security. Herein, the key attributes of hydroxides and oxygen vacancies are experimentally identified in non-stoichiometric indium oxide nanoparticles, In2O3-x(OH)y, that function in concert to reduce CO2 to CO under simulated solar irradiation. © 2014 The Authors.
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页数：10
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