Electroluminescence Characteristics of a New Green-Emitting Phenylphenothiazine Derivative with Phenylbenzimidazole Substituent

被引:15
作者
Ahn, Yeonseon [1 ]
Jang, Da Eun [2 ]
Cha, Yong-Bum [2 ]
Kim, Mansu [1 ]
Ahn, Kwang-Hyun [2 ]
Kim, Young Chul [1 ]
机构
[1] Kyung Hee Univ, Dept Chem Engn, Gyeonggi Do 446701, South Korea
[2] Kyung Hee Univ, Dept Appl Chem, Gyeonggi Do 446701, South Korea
基金
新加坡国家研究基金会;
关键词
Phenylphenothiazine derivative; Donor-acceptor architecture; Green-emitting OLED; DONOR-ACCEPTOR MOLECULES; PHENOTHIAZINE; EMISSION;
D O I
10.5012/bkcs.2013.34.1.107
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new green-emitting material with donor-acceptor architecture, 3,7-bis(1-'-phenylbenzimidazole-2'-yl)-10-phenylphenothiazine (BBPP) was synthesized and its thermal, optical, and electroluminescent characteristics were investigated. Organic light-emitting diodes (OLEDs) with four different multilayer structures were prepared using BBPP as an emitting layer. The optimized device with the structure of [ITO/2-TNATA (40 rim)/BBPP (30 nm)/TPBi (30 nm)/Alq3 (10 nm)/LiF (1 nm)/Al (100 nm)] exhibited efficient green emission. Enhanced charge carrier balance and electron mobility in the organic layers enabled the device to demonstrate a maximum luminance of 31,300 cd/m(2), a luminous efficiency of 6.83 cd/A, and an external quantum efficiency of 1.62% with the CIE 1931 chromaticity coordinates of (0.21, 0.53) at a current density of 100 mA/cm(2).
引用
收藏
页码:107 / 111
页数:5
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