A pillared-layered copper(I) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift

被引：16

作者：

Xin, Bingjing ^{[1
,2
]}

Sang, Jianwei ^{[1
]}

Gao, Yi ^{[1
]}

Li, Guanghua ^{[2
]}

Shi, Zhan ^{[2
]}

Feng, Shouhua ^{[2
]}

机构：

[1] Jilin Inst Chem Technol, Jilin 132022, Jilin, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Jilin, Peoples R China

来源：

RSC ADVANCES | 2018年 / 8卷 / 04期

基金：

中国国家自然科学基金;

关键词：

SELF-ASSEMBLY REACTION; LUMINESCENCE THERMOCHROMISM; IODIDE CLUSTERS; PHOTOLUMINESCENCE PROPERTIES; MECHANOCHROMIC LUMINESCENCE; CUPROPHILIC INTERACTIONS; COORDINATION POLYMERS; CU4I4; CUBANE; COMPLEXES; LIGANDS;

D O I：

10.1039/c7ra11950j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a new copper halide-based compound [Cu6I6Br2C16H32N4] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at ca. 500 nm and ca. 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound 1 show large red shifts of 120 nm and 72 nm, respectively.

引用

页码：1973 / 1978

页数：6

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