Metallization of biologically inspired silica nanotubes

The desire and need for various types of nanostructures have been met with challenges of feasibility, reproducibility, and long fabrication time. To work towards improved bottom-up methods of nanofabrication, we use bacterial flagella as bio-templates for fabricating silica-mineralized nanotubes, which are ideal for the formation of metal nanoparticles or metal oxide nanoparticles. In this study, we show that silica nanotubes formed from flagella templates can be coated with gold, palladium, and iron oxide nanoparticles under mild aqueous conditions. The process was accomplished through reactions including reductive metallization or oxidative hydrolysis. Morphology and chemical composition were analyzed by transmission electron microscopy and energy dispersive X-ray spectroscopy, respectively. The results from these studies provide evidence for the complete coating of silica nanotubes with metal nanoparticles using a simple and fast procedure. (C) 2012 Elsevier B.V. All rights reserved.