One-Dimensional Rod-Like Sb2S3-Based Anode for High-Performance Sodium-Ion Batteries

被引:220
作者
Hou, Hongshuai [1 ]
Jing, Mingjun [1 ]
Huang, Zhaodong [1 ]
Yang, Yingchang [1 ]
Zhang, Yan [1 ]
Chen, Jun [1 ]
Wu, Zhibin [1 ]
Ji, Xiaobo [1 ]
机构
[1] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Sb2S3; rod; anode; sodium-ion battery; electrochemistry; HIGH-CAPACITY; ELECTROCHEMICAL PERFORMANCE; ANTIMONY SULFIDE; CYCLE STABILITY; RATE CAPABILITY; SB; COMPOSITE; LITHIUM; STORAGE; MICROSPHERES;
D O I
10.1021/acsami.5b05509
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Due to the high theoretical capacity of 946 mAh g(-1) Sb2S3 can be employed as promising electrode material for sodium-ion batteries (SIBs). Herein, the sodium storage behaviors of one-dimensional (1D) Sb2S3-based materials (Sb2S3 and Sb2S3@C rods) are successfully studied for the first time, displaying good cyclability and rate capability owing to their unique morphology and structure. Specifically, the Sb2S3@C rods electrode presents greatly enhanced electrochemical properties, resulting from the introduction of thin carbon layers which can effectively alleviate the strain caused by the large volume change and simultaneously improve the conductivity of electrode during cycling. At a current density of 100 mA g(-1), it delivers a high capacity of 699.1 mAh g(-1) after 100 cycles, which corresponds to 95.7% of the initial reversible capacity. Even at a high current density of 3200 mA g(-1), the capacity can still reach 429 mAh g(-1). This achievement may be a significant exploration for develpoing novel ID Sb-based materials or metal sulfide SIBs anodes.
引用
收藏
页码:19362 / 19369
页数:8
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