'Dry bases': carbon dioxide capture using alkaline dry water

被引:48
作者
Dawson, Robert [1 ,2 ]
Stevens, Lee A. [3 ]
Williams, Orla S. A. [3 ]
Wang, Weixing [1 ,2 ,4 ]
Carter, Benjamin O. [1 ,2 ]
Sutton, Sam [1 ,2 ]
Drage, Trevor C. [3 ]
Blanc, Frederic [1 ,5 ]
Adams, Dave J. [1 ,2 ]
Cooper, Andrew I. [1 ,2 ]
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 7ZD, Merseyside, England
[3] Univ Nottingham, Fac Engn, Dept Chem & Environm Engn, Nottingham NG7 2RD, England
[4] S China Univ Technol, Sch Chem & Energy Engn, Guangzhou, Guangdong, Peoples R China
[5] Univ Liverpool, Stephenson Inst Renewable Energy, Liverpool L69 7ZD, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
CO2; CAPTURE; NMR;
D O I
10.1039/c3ee44124e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An alkaline form of 'dry water' -a 'dry base'-is prepared by the high-speed mixing of aqueous solutions of metal carbonates or organic amines with hydrophobic silica nanoparticles. Despite being mostly water, the dry base looks and flows like a powder, and adsorbs CO2 rapidly without any mixing because of its high surface-to-volume ratio. Unlike normal aqueous base solutions, dry bases can be non-corrosive because they do not readily wet surfaces.
引用
收藏
页码:1786 / 1791
页数:6
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