Use of reductive properties of iodotrichlorosilane .2. Chemoselective reduction of alpha,beta-unsaturated ketones and nitriles

被引：9

作者：

Elmorsy, SS ^{[1
]}

ElAhl, AAS ^{[1
]}

Soliman, H ^{[1
]}

Amer, FA ^{[1
]}

机构：

[1] UNIV MANSOURA, FAC SCI, DEPT CHEM, MANSOURA, EGYPT

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 13期

关键词：

D O I：

10.1016/0040-4039(96)00247-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthetic procedure for the selective reduction of alpha,beta-unsaturated ketones and nitriles, using iodotrichlorosilane (ITCS generated in situ from SiCl4-Nal) under mild conditions to produce the corresponding saturated ketone and nitrile compounds in quantitative yields, is described.

引用

页码：2297 / 2298

页数：2

共 9 条

[1] BHATT MV, 1982, SYNTHESIS-STUTTGART, V12, P1048
[2] ELMORSY SS, 1994, Z NATURFORSCH B, V49, P417
[3] THE GENERATION OF CARBONYL-COMPOUNDS FROM ACETALS AND KETALS BY IODOTRICHLOROSILANE (ITCS)
ELMORSY, SS
BHATT, MV
PELTER, A
[J]. TETRAHEDRON LETTERS, 1992, 33 (12) : 1657 - 1660
[4] ELMORSY SS, 1993, INDIAN J CHEM B, V32, P637
[5] A NOVEL ROUTE FOR THE DIRECT SYNTHESIS OF SECONDARY AMIDES FROM ALDEHYDES
ELMORSY, SS
NOUR, MA
KANDEEL, EM
PELTER, A
[J]. TETRAHEDRON LETTERS, 1991, 32 (15) : 1825 - 1826
[6] ELMORSY SS, 1992, MANSOURA J PHARM SCI, V8, P96
[7] REDUCTIVE TRANSFORMATIONS WITH TRIMETHYLSILYL CHLORIDE-SODIUM IODIDE - A NEW SYNTHESIS OF 4H-1,3-OXAZINES
GHERA, E
MAURYA, R
HASSNER, A
[J]. TETRAHEDRON LETTERS, 1989, 30 (35) : 4741 - 4744
[8] KEINAN E, 1990, J ORG CHEM, V55, P2938
[9] A CONVENIENT REDUCTION METHOD OF BETA-PHENYL ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS WITH ME3SICL-NAI-ROH REAGENT
SAKAI, T
MIYATA, K
UTAKA, M
TAKEDA, A
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (03) : 1063 - 1066

← 1 →