Two novel luminescent lanthanide sulfate-carboxylates with an unusual 2-D bamboo-raft-like structure based on the linkages of left- and right-handed helical tubes involving in situ decarboxylation

被引：160
作者：
Sun, YQ
Zhang, J
Yang, GY [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 18期
关键词：
D O I：
10.1039/b602034h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel 2-D bamboo-raft-like lanthanide luminescent materials [Ln(Himc)(SO4)(H2O)](L-n=Dy, Eu; H(2)imc=4-imidazolecarboxylic acid), constructed from alternate left- and right-handed helical tubes, were synthesized and characterized; interestingly, H(2)imc came from the in situ decarboxylation of the 4,5-imidazoledicarboxylic acid (H(3)imdc) in the hydrothermal reactions.
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页码：1947 / 1949
页数：3
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