Two novel luminescent lanthanide sulfate-carboxylates with an unusual 2-D bamboo-raft-like structure based on the linkages of left- and right-handed helical tubes involving in situ decarboxylation

被引:159
作者
Sun, YQ
Zhang, J
Yang, GY [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
关键词
D O I
10.1039/b602034h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two novel 2-D bamboo-raft-like lanthanide luminescent materials [Ln(Himc)(SO4)(H2O)](L-n=Dy, Eu; H(2)imc=4-imidazolecarboxylic acid), constructed from alternate left- and right-handed helical tubes, were synthesized and characterized; interestingly, H(2)imc came from the in situ decarboxylation of the 4,5-imidazoledicarboxylic acid (H(3)imdc) in the hydrothermal reactions.
引用
收藏
页码:1947 / 1949
页数:3
相关论文
共 39 条
  • [1] Two new diamine templated lanthanum sulfates, La2(H2O)2(C4H12N2)(SO4)4 and La2(H2O)2(C2H10N2)3(SO4)6•4H2O, with 3D and 2D crystal structures
    Bataille, T
    Louër, D
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) : 3487 - 3493
  • [2] An organically templated Co(II) sulfate with the kagome lattice
    Behera, JN
    Paul, G
    Choudhury, A
    Rao, CNR
    [J]. CHEMICAL COMMUNICATIONS, 2004, (04) : 456 - 457
  • [3] Breck D.W, 1974, ZEOLITE MOL SIEVES
  • [4] Bunzli J.-C.G., 1989, LANTHANIDE PROBES LI
  • [5] Synthesis, structure, and photoelectronic effects of a uranium-zinc-organic coordination polymer containing infinite metal oxide sheets
    Chen, W
    Yuan, HM
    Wang, JY
    Liu, ZY
    Xu, JJ
    Yang, M
    Chen, JS
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) : 9266 - 9267
  • [6] CHRISTIAN S, 2004, CHEM MATER, V16, P1177
  • [7] Organically templated rare earth sulfates with three-dimensional and layered structures
    Dan, M
    Behera, JN
    Rao, CNR
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (08) : 1257 - 1265
  • [8] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330
  • [9] Synthesis and characterization of four ethylenediamine-templated iron arsenates
    Ekambaram, S
    Sevov, SC
    [J]. INORGANIC CHEMISTRY, 2000, 39 (11) : 2405 - 2410
  • [10] HYDRAZINIUM AS A LIGAND - STRUCTURAL, THERMAL, SPECTROSCOPIC, AND MAGNETIC STUDIES OF HYDRAZINIUM LANTHANIDE DI-SULFATE MONOHYDRATES - CRYSTAL-STRUCTURE OF THE NEODYMIUM COMPOUND
    GOVINDARAJAN, S
    PATIL, KC
    MANOHAR, H
    WERNER, PE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (01): : 119 - 123