Molecular Structures and Second-Order Nonlinear Optical Properties of Ionic Organic Crystal Materials

被引：109
作者：
Liu, Xiu [1 ]
Yang, Zhou [1 ]
Wang, Dong [1 ]
Cao, Hui [1 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Key Lab Funct Mat Mol & Struct Construct, Beijing 100083, Peoples R China
来源：
CRYSTALS | 2016年 / 6卷 / 12期
基金：
中国国家自然科学基金;
关键词：
second-order nonlinear optical material; ionic organic crystal; D-pi-A conjugated molecule; STILBAZOLIUM-SALT; 2ND-HARMONIC GENERATION; SINGLE-CRYSTALS; ELECTROOPTICAL PERFORMANCES; HEMICYANINE DYES; ELECTRON-DONORS; CHROMOPHORES; DERIVATIVES; GROWTH; METHYLPYRIDINIUM;
D O I：
10.3390/cryst6120158
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In recent years, there has been extensive research and continuous development on second-order nonlinear optical (NLO) crystal materials due to their potential applications in telecommunications, THz imaging and spectroscopy, optical information processing, and optical data storage. Recent progress in second-order NLO ionic organic crystal materials is reviewed in this article. Research has shown that the second-order nonlinear optical properties of organic crystal materials are closely related to their molecular structures. The basic structures of ionic organic conjugated molecules with excellent nonlinear optical properties are summarized. The effects of molecular structure, for example, conjugated pi electron systems, electronic properties of donor-acceptor groups, and different counter-anion effects on second order NLO properties and crystal packing are studied.
引用
收藏
页数：19
相关论文
共 79 条
[1]   Large molecular hyperpolarizabilities. Quantitative analysis of aromaticity and auxiliary donor-acceptor effects [J].
Albert, IDL ;
Marks, TJ ;
Ratner, MA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (28) :6575-6582
[2]  
[Anonymous], 2015, ORGANIC ELECTRO OPTI
[3]  
[Anonymous], 1997, Nonlinear optics of organic molecules and polymers
[4]   Preparation and crystal structures of new colorless 4-amino-1-methylpyridinium benzenesulfonate salts for second-order nonlinear optics [J].
Anwar ;
Okada, S ;
Oikawa, H ;
Nakanishi, H .
CHEMISTRY OF MATERIALS, 2000, 12 (04) :1162-1170
[5]   IMPROVED 2ND-HARMONIC GENERATION FROM LANGMUIR-BLODGETT-FILMS OF HEMICYANINE DYES [J].
ASHWELL, GJ ;
HARGREAVES, RC ;
BALDWIN, CE ;
BAHRA, GS ;
BROWN, CR .
NATURE, 1992, 357 (6377) :393-395
[6]   Syntheses, Structures, and Electronic and Optical Properties of Platinum(II) Complexes of 1,3-Bis(imino)benzene-Derived Pincer Ligands [J].
Blackburn, Octavia A. ;
Coe, Benjamin J. ;
Helliwell, Madeleine ;
Raftery, James .
ORGANOMETALLICS, 2012, 31 (15) :5307-5320
[7]   Growth of Ultrathin and Highly Efficient Organic Nonlinear Optical Crystal 4′-Dimethylamino-N-methyl-4-Stilbazolium p-Chlorobenzenesulfonate for Enhanced Terahertz Efficiency at Higher Frequencies [J].
Brahadeeswaran, S. ;
Takahashi, Y. ;
Yoshimura, M. ;
Tani, M. ;
Okada, S. ;
Nashima, S. ;
Mori, Y. ;
Hangyo, M. ;
Ito, H. ;
Sasaki, T. .
CRYSTAL GROWTH & DESIGN, 2013, 13 (02) :415-421
[8]   Engineering of Organic Chromophores with Large Second-Order Optical Nonlinearity and Superior Crystal Growth Ability [J].
Chen, Honghong ;
Ma, Oj ;
Zhou, Yugiao ;
Yang, Zhou ;
Jazbinsek, Mojca ;
Bian, Yongzhong ;
Ye, Ning ;
Wang, Dong ;
Cao, Hui ;
He, Wanli .
CRYSTAL GROWTH & DESIGN, 2015, 15 (11) :5560-5567
[9]   Syntheses and quadratic nonlinear optical properties of salts containing benzothiazolium electron-acceptor groups [J].
Coe, Benjamin J. ;
Harris, James A. ;
Hall, Jonathan J. ;
Brunschwig, Bruce S. ;
Hung, Sheng-Ting ;
Libaers, Wim ;
Clays, Koen ;
Coles, Simon J. ;
Horton, Peter N. ;
Light, Mark E. ;
Hursthouse, Michael B. ;
Garin, Javier ;
Orduna, Jesus .
CHEMISTRY OF MATERIALS, 2006, 18 (25) :5907-5918
[10]   Helquat Dyes: Helicene-like Push-Pull Systems with Large Second-Order Nonlinear Optical Responses [J].
Coe, Benjamin J. ;
Rusanova, Daniela ;
Joshi, Vishwas D. ;
Sanchez, Sergio ;
Vavra, Jan ;
Khobragade, Dushant ;
Severa, Lukas ;
Cisarova, Ivana ;
Saman, David ;
Pohl, Radek ;
Clays, Koen ;
Depotter, Griet ;
Brunschwig, Bruce S. ;
Teply, Filip .
JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (05) :1912-1920
12345678