Synthesis and reaction of a powerful nucleophilic long-chain imidazole-2-aldoxime

被引：0

作者：

Dai, QY ^{[1
]}

Huang, QB ^{[1
]}

Deng, YD ^{[1
]}

机构：

[1] Res Inst Chem Def, Beijing 102205, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 22卷 / 02期

关键词：

N-tetradecylimidazole-2-aldoxime; PNPDPP; parathion; Vx; nucleophilic reaction;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new long-chain oxime N-tetradecylimidazole-2-aldoxime (1) was designed and synthesized. The reactivities, of I and other long-chain oximes with p-nitrophenyl diphenyl phosphate (PNPDPP), p-nitrophenyl diethyl thiophosphate (parathion), and O-ethyl ( s-beta-diisopropylaminoethyl) methyl phosphonothiolate (Vx) were studied. The results showed that 1 was a powerful nucleophile that was 5 similar to 10 times more active than those oximes reported so far and was useful in non-corrosive decontamination of stable and toxic phosphate esters.

引用

页码：130 / 134

页数：5

共 25 条

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