Multiple Phases of Liquid Water

被引：75

作者：

Brovchenko, Ivan ^{[1
]}

Oleinikova, Alla ^{[1
]}

机构：

[1] Dortmund Univ Technol, D-44227 Dortmund, Germany

来源：

CHEMPHYSCHEM | 2008年 / 9卷 / 18期

关键词：

percolation; phase diagrams; phase transitions; supercritical fluids; thermodynamics;

D O I：

10.1002/cphc.200800639

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The history of the study of the anomalies of liquid water, from the 17th century up to the present, is reviewed and the current view on the origin of these anomalies is summarized. The hypothesis of the multiple liquid-liquid transitions of water in the supercooled region is consistent with the available experimental and simulation data and provides physical explanation of water behavior in a wide thermodynamic range. The general character of the liquid-liquid transitions of fluids is discussed and the remaining questions ore formulated

引用

页码：2660 / 2675

页数：16

共 150 条

[1] A general purpose model for the condensed phases of water: TIP4P/2005 [J].