Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes

被引：141

作者：

Fujihara, Tetsuaki ^{[1
]}

Tani, Yosuke ^{[1
]}

Semba, Kazuhiko ^{[1
]}

Terao, Jun ^{[1
]}

Tsuji, Yasushi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 46期

关键词：

alkynes; carboxylation; copper; homogeneous catalysis; silylborane; C-H BONDS; DIRECT CARBOXYLATION; TERMINAL ALKYNES; PALLADIUM; HYDROCARBOXYLATION; SILABORATION; COMPLEXES; CLEAVAGE; TRANSFORMATION; BENZOSILOLES;

D O I：

10.1002/anie.201207148

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silalactones: The copper-catalyzed reaction of internal alkynes with (dimethylphenylsilyl)pinacolborane (Me 2PhSi-B(pin)) as the silicon source and CO 2 at atmospheric pressure afforded silalactones selectively in good to high yields. The silalactones can be used as substrates for the Hiyama cross-coupling reaction as demonstrated for one substrate. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11487 / 11490

页数：4

共 51 条

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[2]

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[3]

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[4]

[Anonymous], 2011, ANGEW CHEM-GER EDIT