Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal-organic framework

被引：66

作者：

Gong, Yun-Nan ^{[1
]}

Meng, Miao ^{[1
]}

Zhong, Di-Chang ^{[1
]}

Huang, Yong-Liang ^{[1
]}

Jiang, Long ^{[1
]}

Lu, Tong-Bu ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 98期

关键词：

SORPTION PROPERTIES; GAS-ADSORPTION; BINDING; TEMPERATURE; CAPACITIES; STABILITY; POLYMERS; EXCHANGE; SERIES; PORE;

D O I：

10.1039/c2cc35461f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mu(4)-Cl bridged anionic sodalite-type porous metal-organic framework (Et2NH2)(3)[(Cu4Cl)(3)(TTCA) (8)]center dot 26DEF was synthesized, in which Et2NH2+ can be exchanged by Li+ cations. The results of gas measurements indicate that Et2NH2+ and Li+ are beneficial for methane and hydrogen storage, respectively.

引用

页码：12002 / 12004

页数：3