Modulating the assembly of organic dye molecules on titania nanocrystals via alkyl chain elongation for efficient mesoscopic cobalt solar cells

被引：64

作者：

Cao, Yiming ^{[1
,2
]}

Cai, Ning ^{[1
,2
]}

Wang, Yinglin ^{[1
]}

Li, Renzhi ^{[1
]}

Yuan, Yi ^{[3
]}

Wang, Peng ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

[3] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2012年 / 14卷 / 23期

基金：

美国国家科学基金会;

关键词：

STRUCTURE-PROPERTY RELATIONSHIPS; TIO2; FILMS; RECOMBINATION DYNAMICS; PHOTOVOLTAICS; PERFORMANCE; SENSITIZER; DESIGN; ELECTROLYTE; CONVERSION; INTERFACE;

D O I：

10.1039/c2cp41314k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Through elongating the end or side alkyl chains of dye molecules, we decorate anatase nanocrystals with a thicker organic assembly featuring a smaller tilt angle of the D-pi-A backbone with respect to the surface normal, which retards the interfacial charge recombination and confers a higher photovoltage output on mesoscopic cobalt solar cells displaying an over 10% power conversion efficiency at the AM1.5G conditions.

引用

页码：8282 / 8286

页数：5

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