A novel tellurophene-containing conjugated polymer with a dithiophenyl diketopyrrolopyrrole unit for use in organic thin film transistors

被引:73
作者
Kaur, Matinder [1 ]
Yang, Da Seul [1 ]
Shin, Jicheol [1 ]
Lee, Tae Wan [1 ]
Choi, Kihang [1 ]
Cho, Min Ju [1 ]
Choi, Dong Hoon [1 ]
机构
[1] Korea Univ, Res Inst Nat Sci, Dept Chem, Seoul 136701, South Korea
基金
新加坡国家研究基金会;
关键词
FIELD-EFFECT TRANSISTORS; ALKYL SIDE-CHAINS; COPOLYMERS; SEMICONDUCTORS; MOBILITY;
D O I
10.1039/c3cc41250d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new tellurophene-based pi-conjugated polymer, PDTDPPTe, was synthesized. PDTDPPTe exhibits a smaller optical band gap (E-g(opt) = 1.25 eV) than thiophene-based PDTDPPT (E-g(opt) = 1.30 eV). Thin-film transistors comprising PDTDPPTe displayed outstanding performance (mu(max) = 1.78 cm(2) V-1 s(-1), I-on/I-off = 10(5-6)).
引用
收藏
页码:5495 / 5497
页数:3
相关论文
共 33 条
[1]   Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].
Allard, Sybille ;
Forster, Michael ;
Souharce, Benjamin ;
Thiem, Heiko ;
Scherf, Ullrich .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098
[2]   Te-Te interactions in inorganic rings with sulfur donors [J].
Bandeira, NAG ;
Veiros, LF ;
Calhorda, MJ ;
Novosad, J .
INORGANICA CHIMICA ACTA, 2003, 356 :319-327
[3]   CONVENIENT SYNTHESIS OF TELLUROPHENE [J].
BARTON, TJ ;
ROTH, RW .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 39 (02) :C66-&
[4]   Impact of the Alkyl Side Chains on the Optoelectronic Properties of a Series of Photovoltaic Low-Band-Gap Copolymers [J].
Biniek, Laure ;
Fall, Sadiara ;
Chochos, Christos L. ;
Anokhin, Denis V. ;
Ivanov, Dimitri A. ;
Leclerc, Nicolas ;
Leveque, Patrick ;
Heiser, Thomas .
MACROMOLECULES, 2010, 43 (23) :9779-9786
[5]   Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].
Cheng, Yen-Ju ;
Yang, Sheng-Hsiung ;
Hsu, Chain-Shu .
CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923
[6]   Influence of heteroaryl group on electrochemical and spectroscopic properties of conjugated polymers [J].
Data, P. ;
Lapkowski, M. ;
Motyka, R. ;
Suwinski, J. .
ELECTROCHIMICA ACTA, 2012, 83 :271-282
[7]  
Devillanova FA, 2007, HANDBOOK OF CHALCOGEN CHEMISTRY: NEW PERSPECTIVES IN SULFUR, SELENIUM AND TELLURIUM, P1, DOI 10.1039/9781847557575
[8]   Electroluminescent materials for white organic light emitting diodes [J].
Farinola, Gianluca M. ;
Ragni, Roberta .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) :3467-3482
[9]  
Fichou D., 1999, Handbook of Oligo- and Polythiophenes
[10]   Atomistic Band Gap Engineering in Donor-Acceptor Polymers [J].
Gibson, Gregory L. ;
McCormick, Theresa M. ;
Seferos, Dwight S. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) :539-547