The effect of liquid phase separation on the Vickers microindentation shear bands evolution in a Fe-based bulk metallic glass

The Vickers microindentation experiments and associated plastic deformation in as-cast and annealed (Fe0.9Ni0.1)(77)Mo5P9C7.5B1.5 bulk metallic glass was conducted. In addition to the bulk indentation behavior, the shear band morphology underneath the Vickers microindenter was examined by employing the bonded interface technique. Microstructural characterization revealed that a liquid phase separation occurred during melting process. Atomic force microscopy of the glassy matrix of the as-cast specimen reveals the composition inhomogeneity induced by the liquid phase separation. This effect generates shear band branching or deflection during the shear band propagation. For the bulk indentation, the trends in the hardness vs. indentation load were found related to the pressure sensitive index and the phase separation process simultaneously. The results show that the as-cast as well as the annealed specimens are deformed through semi-circular and radial shear bands. In addition, in the partially crystalized specimen, the change in the properties and microstructure of the BMG induced by the partial crystallization treatment and phase separation process resulted in tertiary shear bands formation. (C) 2013 Elsevier B.V. All rights reserved.