Stereoselectivity in ring-closing olefin metathesis (RCM) of tethered dihexenoyl derivatives

被引：20

作者：

Arisawa, M ^{[1
]}

Kaneko, H ^{[1
]}

Nishida, A ^{[1
]}

Nakagawa, M ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 07期

关键词：

D O I：

10.1039/b111122c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ring-closing olefin metatheses (RCM) of various tethered dihexenoyl derivatives were examined under various conditions. The E : Z ratios of the resulting double bonds of the cyclic products were determined. The stereochemistry of the resulting olefins was influenced largely by the effects of the template used.

引用

页码：959 / 964

页数：6

共 38 条

[1] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM [J].

Ackermann, L ;

Fürstner, A ;

Weskamp, T ;

Kohl, FJ ;

Herrmann, WA .

TETRAHEDRON LETTERS, 1999, 40 (26) :4787-4790

[2]

[Anonymous], ANGEW CHEM

[3] Synthesis of substituted 1,2-dihydroquinolines and quinolines using ene-ene metathesis and ene-enol ether metathesis [J].

Arisawa, M ;

Theeraladanon, C ;

Nishida, A ;

Nakagawa, M .

TETRAHEDRON LETTERS, 2001, 42 (45) :8029-8033

[4]

Arisawa M, 1997, SYNLETT, P1179

[5]

Arisawa M, 2000, CHEM PHARM BULL, V48, P1593

[6] Concise synthesis of azacycloundecenes using ring-closing metathesis (RCM) [J].

Arisawa, M ;

Kato, C ;

Kaneko, H ;

Nishida, A ;

Nakagawa, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (12) :1873-1876

[7]

Arisawa M, 2000, SYNLETT, P841

[8]

Armstrong SK, 1998, J CHEM SOC PERK T 1, P371

[9] Synthesis of trisubstituted alkenes via olefin cross-metathesis [J].

Chatterjee, AK ;

Grubbs, RH .

ORGANIC LETTERS, 1999, 1 (11) :1751-1753

[10]

Fürstner A, 2001, CHEM-EUR J, V7, P5286, DOI 10.1002/1521-3765(20011217)7:24<5286::AID-CHEM5286>3.0.CO

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