Syntheses, Crystal Structures and Luminescent Properties of Three Inorganic-Organic Hybrid Frameworks Constructed from 4,5-Imidazoledicarboxylate

被引：16

作者：

Wang, Dong-E ^{[1
]}

Wang, Feng ^{[1
]}

Meng, Xiang-Gao ^{[1
]}

Ding, Yu ^{[2
]}

Wen, Li-Li ^{[1
]}

Li, Dong-Feng ^{[1
,3
]}

Lan, She-Ming ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China

[2] Xiaogan Univ, Sch Chem & Mat Sci, Xiaogan, Peoples R China

[3] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210008, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 14期

关键词：

Hydrothermal synthesis; Crystal structure; 4,5-imidazoledicarboxylate; Luminescence; Hydrogen bonds;

D O I：

10.1002/zaac.200800278

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three inorganic-organic hybrid frameworks [Mn(HIMDC)(4,4'-bipyo)(0.5)(H2O)](n) (1), [Cd(H2IMDC)(2)(2,2'-bipyo)] (2) and [Ca(HIMDC)(H2O)(2)center dot H2O](n) (3) (H3IMDC = 4,5-imidazoledicarboxylate 4,4'-bipyo = 4,4'-bipyridine-N,N'-dioxide; 2,2'-bipyo = 2,2'-bipyridine-N,N'-dioxide) have been hydrothermally synthesized and characterized by the elemental analyses, IR spectra, TG analysis and the single crystal diffraction. Both compounds 1 and 3 exhibit 2D layers while 2 is a monomer. It is noteworthy that compound 2 exhibits strong fluorescent emission in the solid state at room temperature.

引用

页码：2643 / 2648

页数：6

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