Syntheses, Crystal Structures and Luminescent Properties of Three Inorganic-Organic Hybrid Frameworks Constructed from 4,5-Imidazoledicarboxylate

被引：16
作者：
Wang, Dong-E [1 ]
Wang, Feng [1 ]
Meng, Xiang-Gao [1 ]
Ding, Yu [2 ]
Wen, Li-Li [1 ]
Li, Dong-Feng [1 ,3 ]
Lan, She-Ming [1 ]
机构：
[1] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China
[2] Xiaogan Univ, Sch Chem & Mat Sci, Xiaogan, Peoples R China
[3] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210008, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 14期
关键词：
Hydrothermal synthesis; Crystal structure; 4,5-imidazoledicarboxylate; Luminescence; Hydrogen bonds;
D O I：
10.1002/zaac.200800278
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three inorganic-organic hybrid frameworks [Mn(HIMDC)(4,4'-bipyo)(0.5)(H2O)](n) (1), [Cd(H2IMDC)(2)(2,2'-bipyo)] (2) and [Ca(HIMDC)(H2O)(2)center dot H2O](n) (3) (H3IMDC = 4,5-imidazoledicarboxylate 4,4'-bipyo = 4,4'-bipyridine-N,N'-dioxide; 2,2'-bipyo = 2,2'-bipyridine-N,N'-dioxide) have been hydrothermally synthesized and characterized by the elemental analyses, IR spectra, TG analysis and the single crystal diffraction. Both compounds 1 and 3 exhibit 2D layers while 2 is a monomer. It is noteworthy that compound 2 exhibits strong fluorescent emission in the solid state at room temperature.
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收藏
页码：2643 / 2648
页数：6
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