Cascade Hydroamination/Redox Reaction for the Synthesis of Cyclic Aminals Catalyzed by a Combined Gold Complex and BrOnsted Acid

被引：85
作者：
He, Yu-Ping [1 ,2 ]
Wu, Hua [1 ,2 ]
Chen, Dian-Feng [1 ,2 ]
Yu, Jie [1 ,2 ]
Gong, Liu-Zhu [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 17期
关键词：
asymmetric catalysis; BrOnsted acid; cyclic aminals; gold; stereoselectivity; H BOND FUNCTIONALIZATION; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; TRANSITION-METAL; RELAY CATALYSIS; COOPERATIVE CATALYSIS; ASYMMETRIC-SYNTHESIS; ALLYLIC ALKYLATION; PHOSPHORIC-ACID; ACTIVATION; ORGANOCATALYSIS;
D O I：
10.1002/chem.201300052
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Relay catalysis: An unprecedented protocol for the synthesis of cyclic aminals has been realized under the relay catalysis of a gold(I)/Brønsted acid binary system to generate cyclic aminals in excellent yields of up to 99 % with moderate to high diastereoselectivity (see scheme; up to 95:5 d.r.). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：5232 / 5237
页数：6
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