Synthesis and characterization of mono- and binuclear iminopyridyl and salicylaldimine Ru(II)-arene complexes

被引：14
|
作者：
Matsinha, Leah C. [1 ]
Mapolie, Selwyn F. [2 ]
Smith, Gregory S. [1 ]
机构：
[1] Univ Cape Town, Dept Chem, ZA-7701 Cape Town, South Africa
[2] Univ Stellenbosch, Dept Chem & Polymer Sci, ZA-7602 Stellenbosch, South Africa
来源：
POLYHEDRON | 2013年 / 53卷
基金：
新加坡国家研究基金会;
关键词：
Ruthenium-arene; Salicylaldimine; Iminopyridyl; Mononuclear; Binuclear; ARENE RUTHENIUM COMPLEXES; RUTHENIUM(II)-ARENE COMPLEXES; ETA(6)-ARENE; PRECURSORS;
D O I：
10.1016/j.poly.2013.01.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A dimeric ruthenium (II)-arene precursor containing a 2-hydroxyethoxy moiety tethered to the arene was reacted with a series of monomeric and dimeric iminopyridyl and salicylaldimine Schiff-base ligands to produce a series of new neutral and cationic mono- and binuclear Ru(II)-arene complexes. All the complexes were characterised using various spectroscopic and analytical techniques including H-1 NMR, C-13 NMR and FT-IR spectroscopy, mass spectrometry, elemental analysis and single-crystal X-ray diffraction. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：56 / 61
页数：6
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