{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)lanthanum(III) methanol disolvate

被引:0
作者
Liu, Fei [1 ]
机构
[1] Eastern Liaoning Univ, Coll Chem Engn & Mat, Dandong 118003, Liaoning Prov, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536808026986
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title dinuclear complex, [NiLa(C19H20N2O4)(NO3)(3)-(CH3OH)(2)]center dot 2CH(3)OH, the Ni-II ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octahedral geometry. The La-III ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-antiprismatic environment. In the crystal structure, intermolecular O-H-O hydrogen bonds connect complex molecules and methanol solvent molecules, forming a two-dimensional network.
引用
收藏
页码:M1207 / U953
页数:12
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