Crystal Structures of Two New One-Dimensional (1-D) Chained Haloplumbates: [H2dabco][Pb2Br6]•H2O and [Hdabco][PbI3]•H2O (dabco=1,4-diazabicyclo[2,2,2]octane)

被引：1

作者：

Hou, Qin ^{[2
]}

Xu, Yue ^{[3
]}

Jin, Juan ^{[1
,4
]}

Zhao, Jin-Jing ^{[1
,4
]}

Yu, Jie-Hui ^{[1
,4
]}

Xu, Ji-Qing ^{[1
,4
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China

[2] Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271018, Shandong, Peoples R China

[3] Jilin Univ, Expt Ctr Testing Sci, Changchun 130023, Jilin, Peoples R China

[4] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2012年 / 23卷 / 02期

关键词：

Haloplumbate; Organic amine; Templating agent; Crystal structure; Hydrothermal synthesis; COPPER(I) HALIDES; IODOPLUMBATE; COMPLEXES; LIGAND;

D O I：

10.1007/s10876-011-0423-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under the hydrothermal conditions, the simple self-assemblies of the Pb2+ salts, NaBr/KI and dabco in acidic aqueous solutions created two protonated dabco-templated chained haloplumbates [H(2)dabco][Pb2Br6]center dot H2O and [Hdabco][PbI3]center dot H2O (dabco = 1,4-diazabicyclo[2,2,2]octane). Compound possesses the 1-D double-chain structure based on the Pb2Br9 subunits, while compound shows the simple 1-D single-chain structure based on the PbI6 octahedra. Ultraviolet-visible spectrum analysis indicates that compound is the potential semiconductor material.

引用

页码：237 / 245

页数：9

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