Ionic Conductivity and Battery Characteristic Studies on PEO+NaClO3 Polymer Electrolyte

被引：15

作者：

Chandrasekaran, R. ^{[1
]}

Mangani, I. Ruth ^{[1
]}

Vasanthi, R. ^{[1
]}

Selladurai, S. ^{[1
]}

机构：

[1] Anna Univ, MIT, Dept Phys, Solid State Ion Lab, Madras 600044, Tamil Nadu, India

来源：

IONICS | 2001年 / 7卷 / 1-2期

关键词：

Ionic Conductivity; Polymer Electrolyte; NaClO3; Ethylene Oxide; Electrochemical Cell;

D O I：

10.1007/BF02375472

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid polymer electrolyte films based on poly (ethylene oxide) PEO complexed with NaClO(3) have been prepared by a solution-cast technique. The solvation of Na(+) ion with PEO is confirmed by XRD and IR studies. Measurements of the a. c. conductivity in the temperature range 308 - 378 K and the transference numbers have been carried out to investigate the charge transport in this polymer electrolyte system. Transport number data show that the charge transport in this polymer electrolyte system is predominantly due to ions. The highest conductivity (2.12.10(-4) S/cm) has been observed for the 70:30 composition. Using the polymer electrolyte solid state electrochemical cells have been fabricated. The various cell parameters are evaluated and reported.

引用

页码：88 / 93

页数：6

共 23 条

[1]

ANNAND MB, 1986, ANNU REV MATER SCI, V16, P245

[2]

Armand M. B., 1987, POLYM ELECTROLYTE RE, P1

[3]

Chandra A., 1992, SOLID STATE IONICS M, P397

[4]

FAUTEUX D, 1986, J ELECTROCHEM SOC, V133, P307

[5]

GREENBAUM SG, 1988, SOLID STATE IONICS, V28, P235

[6]

GREENBAUM SG, 1988, J ELECTROCHEM SOC, V135, P1042

[7] PROTON-CONDUCTING POLYMER ELECTROLYTE .1. THE POLYETHYLENE OXIDE + NH4CIO4 SYSTEM [J].

HASHMI, SA ;

KUMAR, A ;

MAURYA, KK ;

CHANDRA, S .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1990, 23 (10) :1307-1314

[8] PHASE-BEHAVIOR AND CONDUCTIVITY IN POLY(ETHYLENE OXIDE)-SODIUM THIOCYANATE SYSTEMS [J].

LEE, YL ;

CRIST, B .

JOURNAL OF APPLIED PHYSICS, 1986, 60 (08) :2683-2689

[9]

MacCallum J.V., 1987, POLYM ELECTROLYTES R

[10] PROTON CONDUCTING POLYMER ELECTROLYTES - POLYETHYLENE OXIDE + (NH4)2SO4 SYSTEM [J].

MAURYA, KK ;

HASHMI, SA ;

CHANDRA, S .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1992, 61 (05) :1709-1716

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