Improvement of the field emission of carbon nanotubes by hafnium coating and annealing

被引:43
作者
Zhang, JH [1 ]
Yang, CR
Wang, YJ
Feng, T
Yu, WD
Jiang, J
Wang, X
Liu, XH
机构
[1] Univ Elect Sci & Technol China, Inst Microelect & Solid State Elect, Chengdu 610054, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, Shanghai 200050, Peoples R China
关键词
D O I
10.1088/0957-4484/17/1/043
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Despite the promising field emission properties, as-grown carbon nanotubes (CNTs) are far from perfect and need improvement. We report on the field electron emission properties of hafnium coated CNTs. The result shows hafnium carbide (HfC) can be formed on the surface of CNT films at an annealing temperature of 1200 degrees C. This treatment improves the field emission current density, emission uniformity and emission stability of CNT films. The improvement of field emission by Hf coating on the CNT surface benefits from the formation of HfC, which is conductive, inert, robust and of low work function. This approach may provide an effective method for the modification of the field emission of CNTs.
引用
收藏
页码:257 / 260
页数:4
相关论文
共 15 条
[1]   Field emission properties of multiwalled carbon nanotubes [J].
Bonard, JM ;
Maier, F ;
Stöckli, T ;
Châtelain, A ;
de Heer, WA ;
Salvetat, JP ;
Forró, L .
ULTRAMICROSCOPY, 1998, 73 (1-4) :7-15
[2]   Carbon nanotube films as electron field emitters [J].
Bonard, JM ;
Croci, M ;
Klinke, C ;
Kurt, R ;
Noury, O ;
Weiss, N .
CARBON, 2002, 40 (10) :1715-1728
[3]   Influence of the deposition conditions on the field emission properties of patterned nitrogenated carbon nanotube films [J].
Bonard, JM ;
Kurt, R ;
Klinke, C .
CHEMICAL PHYSICS LETTERS, 2001, 343 (1-2) :21-27
[4]   Electronic structure and localized states at carbon nanotube tips [J].
Carroll, DL ;
Redlich, P ;
Ajayan, PM ;
Charlier, JC ;
Blase, X ;
DeVita, A ;
Car, R .
PHYSICAL REVIEW LETTERS, 1997, 78 (14) :2811-2814
[5]   The environmental stability of field emission from single-walled carbon nanotubes [J].
Dean, KA ;
Chalamala, BR .
APPLIED PHYSICS LETTERS, 1999, 75 (19) :3017-3019
[6]   Anti-emission characteristics of the grid coated with hafnium film [J].
Jiang, J ;
Jiang, BY ;
Ren, CX ;
Feng, T ;
Wang, X ;
Liu, XH ;
Zou, SC .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2005, 23 (03) :506-511
[7]   FIELD-EMISSION FROM HAFNIUM CARBIDE [J].
MACKIE, WA ;
MORRISSEY, JL ;
HINRICHS, CH ;
DAVIS, PR .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (04) :2852-2856
[8]   Contributions to the work function: A density-functional study of adsorbates at graphene ribbon edges [J].
Ramprasad, R ;
von Allmen, P ;
Fonseca, LRC .
PHYSICAL REVIEW B, 1999, 60 (08) :6023-6027
[9]   Fabrication and characterization of HfC coated Si field emitter arrays [J].
Sato, T ;
Yamamoto, S ;
Nagao, M ;
Matsukawa, T ;
Kanemaru, S ;
Itoh, J .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2003, 21 (04) :1589-1593
[10]  
Toth L. E., 1971, TRANSITION METAL CAR