Synthesis and photovoltaic properties of a donor-acceptor polymer containing both dithieno[3,2-b:2′,3′-d]pyrrole and fluorene as donor units

被引：9

作者：

Song, Haiyang ^{[1
,2
]}

Tong, Hui ^{[1
]}

Xie, Zhiyuan ^{[1
]}

Wang, Lixiang ^{[1
]}

Wang, Fosong ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

POLYMER | 2012年 / 53卷 / 22期

基金：

中国国家自然科学基金;

关键词：

Polymer solar cells; DTP-based polymers; Conjugated polymers; HETEROJUNCTION SOLAR-CELLS; CONJUGATED POLYMERS; EFFICIENT; POLYFLUORENE; PERFORMANCE; COPOLYMERS; DESIGN;

D O I：

10.1016/j.polymer.2012.09.013

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new donor-acceptor polymer (PDTPDBF), containing both dithieno[3,2-b:2',3'-d]pyrrole (DTP) and fluorene as electron-donating units and benzo-2,1,3-thiadiazole (BT) as electron-accepting unit, was synthesized by Suzuki coupling reaction. Its optical, thermal, electrochemical and photovoltaic properties have been investigated. Compared with typical DTP-based donor-acceptor polymers, PDTPDBF showed a distinct low HOMO level (-5.47 eV). Theoretical calculation attributed this low-lying HOMO level to both the weaker electron-donating ability of the fluorene unit and the moderately twisted conformation between the fluorene unit and the BT unit. Polymer solar cells (PSCs) based on PDTPDBF and PC71BM (1:2, w/w) exhibited an open circuit voltage of 0.84 V and a power conversion efficiency (PCE) of 4.2%, both of which are relatively high values for DTP-based photovoltaic polymers. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：5103 / 5108

页数：6

共 47 条

[1] Fused ring thiophene-based poly(heteroarylene ethynylene)s for organic solar cells [J].

Ashraf, Raja Shahid ;

Gilot, Jan ;

Janssen, Rene A. J. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (10) :1759-1766

[2] Green Dioxythiophene-Benzothiadiazole Donor-Acceptor Copolymers for Photovoltaic Device Applications [J].

Beaujuge, Pierre M. ;

Subbiah, Jegadesan ;

Choudhury, Kaushik Roy ;

Ellinger, Stefan ;

McCarley, Tracy D. ;

So, Franky ;

Reynolds, John R. .

CHEMISTRY OF MATERIALS, 2010, 22 (06) :2093-2106

[3] Solar-Energy Production and Energy-Efficient Lighting: Photovoltaic Devices and White-Light-Emitting Diodes Using Poly(2,7-fluorene), Poly(2,7-carbazole), and Poly(2,7-dibenzosilole) Derivatives [J].

Beaupre, Serge ;

Boudreault, Pierre-Luc T. ;

Leclerc, Mario .

ADVANCED MATERIALS, 2010, 22 (08) :E6-+

[4] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[5] Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices [J].

Chen, Junwu ;

Cao, Yong .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1709-1718

[6] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[7] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Dennler, Gilles ;

Scharber, Markus C. ;

Brabec, Christoph J. .

ADVANCED MATERIALS, 2009, 21 (13) :1323-1338

[8]

Frisch M. J., 2004, GAUSSIAN 03 REVISION

[9] Conjugated polymer-based organic solar cells [J].

Guenes, Serap ;

Neugebauer, Helmut ;

Sariciftci, Niyazi Serdar .

CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338

[10] Advanced materials and processes for polymer solar cell devices [J].

Helgesen, Martin ;

Sondergaard, Roar ;

Krebs, Frederik C. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (01) :36-60

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