Heterogeneous shear elasticity of glasses: the origin of the boson peak

被引:156
作者
Marruzzo, Alessia [1 ,2 ]
Schirmacher, Walter [1 ,3 ]
Fratalocchi, Andrea [2 ]
Ruocco, Giancarlo [1 ]
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[2] KAUST, Fac Elect Engeneering Appl Math & Computat Sci, PRIMALIGHT, Thuwal 239556900, Saudi Arabia
[3] Johannes Gutenberg Univ Mainz, Inst Phys, D-55099 Mainz, Germany
关键词
THERMAL-CONDUCTIVITY; VIBRATIONAL EXCITATIONS; NEUTRON-SCATTERING; MOLECULAR-DYNAMICS; SOLIDS; MODEL; LOCALIZATION; BEHAVIOR; SYSTEMS;
D O I
10.1038/srep01407
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The local elasticity of glasses is known to be inhomogeneous on a microscopic scale compared to that of crystalline materials. Their vibrational spectrum strongly deviates from that expected from Debye's elasticity theory: The density of states deviates from Debye's law, the sound velocity shows a negative dispersion in the boson-peak frequency regime and there is a strong increase of the sound attenuation near the boson-peak frequency. By comparing a mean-field theory of shear-elastic heterogeneity with a large-scale simulation of a soft-sphere glass we demonstrate that the observed anomalies in glasses are caused by elastic heterogeneity. By observing that the macroscopic bulk modulus is frequency independent we show that the boson-peak-related vibrational anomalies are predominantly due to the spatially fluctuating microscopic shear stresses. It is demonstrated that the boson-peak arises from the steep increase of the sound attenuation at a frequency which marks the transition from wave-like excitations to disorder-dominated ones.
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页数:7
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