Hypervalent Iodine Reagents as Powerful Electrophiles

被引：135
作者：
Brown, Michael [1 ]
Farid, Umar [1 ]
Wirth, Thomas [1 ]
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
来源：
SYNLETT | 2013年 / 24卷 / 04期
基金：
英国工程与自然科学研究理事会;
关键词：
alkenes; catalysis; electrophiles; hypervalent iodine; stereoselective synthesis; M-CHLOROPERBENZOIC ACID; DIARYLIODONIUM SALTS; ALPHA-TOSYLOXYLATION; KETONES; ALKENES; ARYLATION; ALCOHOLS; IBX; SPIROLACTONIZATION; AZIRIDINATION;
D O I：
10.1055/s-0032-1318103
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hypervalent iodine reagents have been investigated as very powerful electrophiles in many different reactions. Efficient formation of new carbon-heteroatom bonds as well as carbon-carbon bonds can be achieved typically under mild reaction conditions with these metal-free reagents. Enantiomerically pure reagents provide the potential for stereoselective reactions and this aspect is highlighted in this account.
引用
收藏
页码：424 / 431
页数：8
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