The kinetics of acid-catalyzed decomposition of decanepersulfonic acid

被引：2

作者：

Zaripov, RN ^{[1
]}

Mukhametzyanova, AA ^{[1
]}

Safiullin, RL ^{[1
]}

Komissarov, VD ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 01期

关键词：

decanepersulfonic acid; decomposition; acid catalysis; kinetics;

D O I：

10.1007/BF02494430

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of thermal decomposition of decanepersulfonic acid (RSO2OOH, R = C10H21) in CCl4 in the presence of cyclohexanesulfonic and trifluoroacetic acids at 323-343 K was studied. The reaction has an autocatalytic character. The kinetics of consumption of the persulfonic acid is described by the equation -d[RSO2OOH]/dt = k(1)[RSO2OOH] + k(2)[RSO2OOH].[HX].

引用

页码：201 / 202

页数：2

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