Heterogeneous Platinum Catalysts for Direct Synthesis of Trimethylamine by N-Methylation of Ammonia and Its Surrogates with CO2/H2

被引：20
|
作者：
Toyao, Takashi [1 ,2 ]
Siddiki, S. M. A. Hakim [1 ]
Ishihara, Keisuke [1 ]
Kon, Kenichi [1 ]
Onodera, Wataru [1 ]
Shimizu, Ken-ichi [1 ,2 ]
机构：
[1] Hokkaido Univ, Inst Catalysis, N-21,W-10, Sapporo, Hokkaido 0010021, Japan
[2] Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries, Katsura, Kyoto 6158520, Japan
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 01期
基金：
日本学术振兴会;
关键词：
Carbon dioxide (CO2); N-Methylation; Trimethylamine synthesis; CARBON-DIOXIDE; MOLECULAR-HYDROGEN; AMINES; CO2;
D O I：
10.1246/cl.160875
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Direct synthesis of trimethylamine through N-methylation of NH3 or its surrogate (NH4HCO3) with both CO2 and H-2 has been achieved by employing Pt and MoOx coloaded TiO2 (Pt-MoOx/TiO2). Pt-MoOx/TiO2 was found to be superior to other supported Pt and transition-metal-loaded MoOx/TiO2 catalysts for the trimethylamine synthesis process.
引用
收藏
页码：68 / 70
页数：3
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